Effect of Filler Nature on Chemical Resistance and Microhardness of Epoxy Composite Films
DOI:
https://doi.org/10.15330/pcss.16.3.528-533Keywords:
water absorption, , chemical stability microhardness, epoxy composites, physical – chemical propertiesAbstract
We investigated the processes of water absorption, chemical stability and microhardness of films of epoxy composites that contained as the polymer matrix the epoxy resin UP-655 and mineral fillers: graphite, mica, aluminum oxide at their content (0 - 30 % mass). It found that introduction of mineral fillers significantly affects on all complex of operating characteristics of the films. Increase of filler content, especially mica, to 20 %, resulting in slower process and reducing the quantity of absorbed moisture by films. In the study of physical and mechanical properties of filled epoxy composites was established that the introduction of mineral filler significantly affects their microhardness, and the nature of the exposure is determined by the type and filler content.
References
H. Li, K. Nevіll, Dovіdkove kerіvnictvo po epoksidnih smol. Per.z angl./Pod red. N.V. Aleksandrova (Energіya, Moskva, 1973).
Ju.S. Lipatov / Pod obshh. red. Fiziko-himija mnogokomponentnyh polimernyh sistem (Naukova dumka, Kiev, 1986).
T.E. Lipatova, L.S. Shejnina, Mineral'nye napolniteli i ih rol' v processe formirovanija polimerov. V kn.: Kataliz i mehanizm reakcii obrazovanija polimerov (Naukova dumka, Kiev, 1980).
Ju.S. Zajcev, Ju.S. Kochergin, M.K. Pakter, R.V. Kucher, Jepoksidnye oligomery i kleevye kompozicii (Naukova dumka, Kiev, 1990).
Jenciklopedija polimerov: V 3 t.- M.: Sov. Jencikl. 1-3, (1972-1977).
І.G. Thіr, T.V. Gumenec'kij, Fіziko-hіmіja polіmerіv: Navch.posіbnik (Vid.NU ”L'vіvs'ka polіtehnіka”, L'vіv, 2005).
A. Vorobjov, Komponenti ta tehnologіyi (8), 25( 2003).
A.V. Buketov, Fіziko-hіmіchnі procesi pri formuvannі epoksikompozitnih materіalіv / Buketov A.V., Stuhljak P.D., Kal'ba E.M. (Zbruch.Ternopіl', 2005).
V.P. Zakordons'kij, Zhurn. prikl. himii (68), 9 (1995).
A. Budnicki, The influence of water on some properties of epoxy composites. – Crosslinked E poxides. Prag. Meet. Macromol. 9 th Discuss. Conf (Prag.1986), r.20.
Ju.S. Kochergin, T.A. Kulik, A.F. Predko, Plast. massy (11), 29 (1985).
V.A. Lipskaja, A.M Ustinova, O.V. Goncharova i dr. Plast. Massy (8), 9 (1986).
Ju.A. Anisimov, Ju.N. Anisimov, Plasticheskie massy (2), 47 (2007).
G.I. Artemova, V.V. Matjuhin, V.A. Talynov, Vlijanie granicy razdela polimer-napolnitel' na process otverzhdenija sljudosoderzhashhih jepoksidnyh kompaundov.- V kn.”Rabotosposobnost' polimernyh materialov dlja nizkovol'tnoj izoljacii. Materialy seminara”. Moskva, 46 (1985).