Hydrogen Sorption Properties, Thermal Stability and Kinetics of Hydrogen Desorption From the Hydride Phase of The MgH2 of a Mechanical Alloys of Magnesium with Ti, Ni and Y

O. G. Ershova; V. D. Dobrovolsky; Yu. M. Solonin

doi:10.15330/pcss.21.1.167-175

Authors

O. G. Ershova Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine
V. D. Dobrovolsky Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine
Yu. M. Solonin Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine

DOI:

https://doi.org/10.15330/pcss.21.1.167-175

Keywords:

mechanical alloy, hydride MgH2, thermodesorption spectroscopy, hydrogen-sorption properties, thermal stability, kinetics of hydrogen desorption

Abstract

The mechanical alloys-composite MАs (Mg +10 % wt.Ti + 5 % wt.Y and Mg +10 % wt.Ni + 5 % wt.Y) were synthesized. The phase content, microstructure, the thermal stability, kinetics of hydrogen desorption from the MgH₂ hydride phase of the obtained MAs were studiedby using XRD, SEM, TDS methods. It has been established that the addition of Ti + Y and Ni + Y to magnesium leads to significant improvement in the kinetics of hydrogen desorption from the MgH₂ hydride phase, which is evidenced by a significant reduction (in 6 and 15 times)in the time of release of all hydrogen from MA1 and MA2, respectively. Due to, Ti, Ni,Y alloying, the decrease in the thermodynamic stability of MgH₂ is not found.

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