Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues

  • S. Imamaliyeva Institute of Catalysis and Inorganic Chemictry
Keywords: thallium-REE tellurides, differential-thermal analysis, powder X-ray diffraction, crystal lattice

Abstract

The novel ternary compounds Tl4GdTe3 and Tl4DyTe3 ­- structural analogs of Tl5Te3 (Sp.gr.I4/mcm), were synthesized and identified by DTA and XRD methods. From powder XRD data, their crystal lattices parameters were calculated: a=8.8766(7), c=13.0846 (13) Å, Z=4 (Tl4GdTe3); a=8.8588 (9), c=13.0524(16) Å, Z=4 (Tl4DyTe3). It was found that the synthesized compounds melt with decomposition by peritectic reactions at 770 and 762 K, respectively.

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Published
2020-09-30
How to Cite
ImamaliyevaS. (2020). Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues. Physics and Chemistry of Solid State, 21(3), 492-495. https://doi.org/10.15330/pcss.21.3.492-495
Section
Scientific articles