Investigation and Study of CaO-Borate Glass

Array

Authors

  • D. Priya Manomaniam Sundaranar University, Tirunelveli
  • S. Thirumaran Annamalai University

DOI:

https://doi.org/10.15330/pcss.22.3.407-414

Keywords:

metallic glasses, acoustical parameters, Debye temperature, elastic moduli, optical properties

Abstract

Recent days the special interest towards Glasses is specifically due to their vast applications that they range. Glass series Calcium borate metallic glass (CaO–B2O3) has been prepared by melt quenching technique. CaO influences like density/molar volume ratio on the properties have analyzed and glass sample different modulus has found between them. The optical properties such as direct and indirect bandgap, Urbach energy, band gap, which also includes heat‐treated glasses, has studied by Fourier transform infrared spectroscopy and UV‐visible, respectively. According to this model elastic moduli increase, this is because of the CaO content increase. The Debye temperature, elastic moduli, other acoustic parameters and Poisson's ratio has acquired from experimental data. The obtained results show that the CaO enters into the glass network as a modifier by occupying increasing the nonbridging oxygen atoms (NBOs) and the interstitial spaces in the network.

Author Biography

S. Thirumaran, Annamalai University

Department of Physics

References

S. Ghosh, A.D. Sharma, P. Kundu, S. Mahanty, R.N. Basu, J. Non-Cryst. Solids 354, 4081 (2008); https://doi.org/10.1016/j.jnoncrysol.2008.05.036.

X. Yang, L. Zhang, X. Chen, X. Sun, G. Yang, X. Guo, H. Yang, C. Gao, Z. Gou, J. Non-Cryst. Solids 358,1171 (2012). https://doi.org/10.1016/j.jnoncrysol.2012.02.005.

Manupriya, K. S. et.al., physica status solidi (a), Volume203, Issue10, August 2006, Pages 2356-2364. https://doi.org/10.1002/pssa.200622140.

M. Tanveer, et.al, CrystEngCom 16, 5290–5300, (2014). https://doi.org/10.1039/C4CE00090K.

Z. Wang, C. Shu, K. Chou, Inter. J. Sci. Research. 51, 1021 (2011) https://doi.org/10.2355/isijinternational.51.1021.

H. Doweidar, D. EI-Damrawia, M. Al-Zaibania, Vibrational Spectroscopy68, 91 (2013) https://doi.org/10.1016/j.vibspec.2013.05.015.

S.S. Rojas, K. Yukimitu, A.S.S. Camargo, L.A.O. Nunes, A.C. Hernandes, J. NonCryst. Solids 352,3608 (2006). https://doi.org/10.1016/j.jnoncrysol.2006.02.128.

A.M. Abdelghany, H.A. ElBatal, F.M. EzzElDin, Spectrochim Acta A 149,788 (2015). 10.1016/j.saa.2015.04.105.

A. Makishima, J.D. Mackenzie, J Non-Cryst Solids 17,147 (1975). https://doi.org/10.1016/0022-3093(73)90053-7.

M. Ren, S. Cai, W. Zhang, T. Liu, X. Wu, P. Xu, D. Wang, J Non-Cryst Solids 380, 78 (2013) https://doi.org/10.1016/j.jnoncrysol.2013.09.007.

V. Rajendran, A. Nishara Begum, M.A. Azooz, and F.H. El-Batal, Biomater.4263 (2002) https://doi.org/10.1016/s0142-9612(02)00189-8.

B.P.C.Rao, M.T.Shyamsunder, C.Babu Rao, D.K.Bhattacharya, BaldevRaj Non-destructive Testing '92, 1992, Pages 346-350, https://doi.org/10.1016/B978-0-444-89791-6.50075-5

Sujata Sanshi, SaitaDuhan, Ashish Agarwal, Praveen Aghamkar, J. All. Comp. 488 454 (2009) https://doi.org/10.1016/j.jallcom.2009.09.009.

V. Rajendran, N. Palanivelu, B.K. Chaudhuri, K. Goswami, Phys.Status Solidi A, 191,445 (2002), https://doi.org/10.1002/pssa.200622160.

E.A. Abou Neel, W. Chrzanowski, S.P. Valappil,J Non Cryst Solids355, 991 (2009) https://doi.org/10.1016/j.jnoncrysol.2009.04.016.

M. Marezio, H.A. PlettingerW.H. Zachariasen, Acta Crystallographica 16(5),390 (1963) https://doi.org/10.1107/S0365110X63001031.

C.C. Wagner,V. Ferraresi,R. CurottoPis Diez, E.J. Baran, Biological Trace Element Research 122(1), 64 (2008) https://doi.org/10.1007/s12011-007-8060-0.

A. Makishima, J.D. Mackenzie, J. Non. Cryst. Solids 17, 147 (1975) https://doi.org/10.1016/0022-3093(75)90047-2.

V. Rajendran, F.A. Khaliafa, H.A. El-Batal, Indian J. Phys. 69A, 237 (1995) https://doi.org/10.1016/j.ceramint.2012.01.026.

D.C. Hofmann, J.Y. Suh, A. Wiest, and W. Johnson, Scripta Materialia 59(7), 684 (2008) https://doi.org/10.1016/j.scriptamat.2008.05.046.

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Published

2021-07-16

How to Cite

Priya, D., & Thirumaran, S. (2021). Investigation and Study of CaO-Borate Glass: Array. Physics and Chemistry of Solid State, 22(3), 407–414. https://doi.org/10.15330/pcss.22.3.407-414

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Section

Scientific articles (Physics)