Impact of Cd+2  substitutions on structural and mechanical properties of Co0.6Ni0.4-xCdxFe2O4 (0.00≤ x≤0.40) system

P.  Kashid; S.N. Mathad; Mahadev R.  Shedam

doi:10.15330/pcss.24.4.595-602

Authors

P. Kashid K.L.E Institute of Technology, Hubballi, Karnataka, India
S.N. Mathad KLE Institute of Technology, Huballi, India
Mahadev R. Shedam Visvesvaraya Technological University, Jnana Sangama, Belagavi, India

DOI:

https://doi.org/10.15330/pcss.24.4.595-602

Keywords:

Co-precipitation method, cobalt ferrite, Cd substitution, texture coefficients, vibrational modes, mechanical properties

Abstract

This article presents the structural and mechanical properties of Co_0,6Ni_0,4-xCd_xFe₂O₄spinel ferrite nanoparticles. The as prepared samples were characterized by thermo-gravimetric differential thermal analysis to examine their phase transition. TGA/DTA analysis confirmed the reaction is endothermic in nature and the process completion temperature around 714.24oC is good for annealing the prepared ferrite powder. X-ray diffraction pattern revealed, Co_0,6Ni_0,4-xCd_xFe₂O₄ have been well crystallized to spinel crystal structure. The average crystallite size ranging from 14.52nm to 16.92nm. FTIR spectra showed, two significant absorption bands (ν₁ and ν₂) in between 400 cm⁻¹and 600 cm⁻¹confirmed the spinel structured ferrites. Morphological observations revealed, the grain size of prepared ferrites lies in the range 0.85 to 0.21 μm. Raman spectra peak positions of both tetrahedral and octahedral sublattice shifted towards higher energy position.

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