Structural, Growth and Optical Characterization of Guanidinium Sulphanilate (GSA) Single Crystal

Authors

  • R. Sreedevi Department of Physics, Aditanar College of Arts and Science, Tiruchendur, Tamilnadu, India
  • A. S. I. Joy Sinthiya PG and Research Department of Physics, The M.D.T. Hindu College, Tirunelveli,Tamilnadu, India
  • S. C. Vella Durai PG and Research Department of Physics, Sri Paramakalyani College, Alwarkurichi, Tenkasi, Tamilnadu, India
  • T. Balu Department of Physics, Aditanar College of Arts and Science, Tiruchendur, Tamilnadu, India
  • P. Murugakoothan Department of Physics, C.Kandaswamy Naidu College For Men, Chennai, Tamilnadu, India

DOI:

https://doi.org/10.15330/pcss.25.2.278-283

Keywords:

Crystal Growth, Hydrogen bond, GSA, Optical, Structure

Abstract

Guanidine Sulphanilate (GSA) single crystal was grown by slow evaporation growth method. Single crystal X-ray diffraction studies show that the crystal grows in a centro symmetric monoclinic system and its space group is P21/c. Optical studies were carried out using UV visible spectroscopy and the grown crystal shows the the lower cutoff wavelength of 220 nm. Photoluminescence studies show that GSA crystals have good luminescence properties. Laser damage threshold was found to be 0.24GW/cm2. Nonlinear optical studies show green light emission.

References

C. Razzetti, M. Ardoino, L. Zanotti, M. Zha, C. Paorici, Solution Growth and Characterisation of L-alanine Single Crystals, Cryst. Res. Technol, 37, 456 (2002); https://doi.org/10.1002/1521-4079(200205)37:5<456::AID-CRAT456>3.0.CO;2-M.

S. Sakthy Priya, K. Balakrishnan, A. Lakshmanan, P. Surendran, P. Rameshkumar, K. Kannan, P. Geetha, T. A. Hegde, G. Vinitha, Crystal growth and characterization of Benzimidazolium salicylate single crystal for nonlinear optical studies and antibacterial activity. Physics and Chemistry of Solid State, 21(3), 377 (2020); https://doi.org/10.15330/pcss.21.3.377-389.

P. N. Prasad, D. J. Williams, Introduction to Nonlinear Optical Effects in Molecules and Polymers, (Willey, New York, 1990).

G. Marudhu, T. Baraniraj, S. Krishnan, G. Vijayaragavan, K. Kannan, G. Palani, V. Chithambaram, Growth, structural, optical and mechanical studies on Amino acids doped Nonlinear optical sodium acid phthalate single crystals. Physics and Chemistry of Solid State, 23(1), 45 (2022); https://doi.org/10.15330/pcss.23.1.45-51.

V. Ivanitska, P. Fochuk, Polishing of CdTe, Cd(Zn)Te, Cd(Mn)Te Single Crystals by Iodine in Dimethylformamide Physics and Chemistry of Solid State, 23(2), 322 (2022); https://doi.org/10.15330/pcss.23.2.322-327.

S. Nandhini, P. Murugakoothan, Crystal structure, Hirshfeld surface, DFT calculations of guanidinium 4-hydroxybenzoate monohydrate (GuB) single crystal: A potential candidate for nonlinear optical applications,J. Mol. Struct., 113, 110714 (2020); https://doi.org/10.1016/j.molstruc.2020.129736.

S. Gokov, Y. Kazarinov, S. Kalenik, V. Kasilov, T. Malykhina, Y. Rudychev, V. Tsiats’ko, Research of interaction processes of fast and thermal neutrons with solution of organic dye methyl orange. East European Journal of Physics, 4, 130 (2021); https://doi.org/10.26565/2312-4334-2021-4-16.

S. A. Farokhi, S. T. Nandibewoor, Kinetic, mechanistic and spectral studies for the oxidation of sulfanilic acid by alkaline hexacyanoferrate(III),Tetrahedron, 59, 7595 (2003); https://doi.org/10.1016/S0040-4020(03)01148-7.

F. Blasco, L. Perello, J. Latorre, J. Borras, S. G. Granda, Cobalt(II), Nickel(II), and Copper(II) complexes of sulfanilamide derivatives: Synthesis, spectroscopic studies, and antibacterial activity. Crystal structure of [Co(sulfacetamide)2(NCS)2], J. Inorg. Biochem. 61, 143 (1996); https://doi.org/10.1016/0162-0134(95)00053-4.

S. Ferrer, J. Borras, E. G. Espana, Complex formation equilibria between the acetazolamide ((5-acetamido-1,3,4-thiadiazole)-2-sulphonamide), a potent inhibitor of carbonicanhydrase, and Zn(II),Co(II), Ni(II) and Cu(II) in aqueous and ethanol-aqueous solutions.J. Inorg. Biochem., 39, 297 (1990); https://doi.org/10.1016/0162-0134(90)80028-V.

S. Semin, X. Li, Y. Duan, Nonlinear Optical Properties and Applications of Fluorenone Molecular Materials,Adv. Opt.l Mater., 9, 2100327 (2021); https://doi.org/10.1002/adom.202100327.

Z. Machova, I. Nemec, K. Teubner, P. Nemec, P. Vanek, Z. Micka, The crystal structure, vibrational spectra, thermal behaviour and second harmonic generation of aminoguanidinium(1+) hydrogen L-tartrate monohydrate,J. Mol. Srtucture, 832, 101 (2007); https://doi.org/10.1016/j.molstruc.2006.08.006.

M. P. Nancy, J. Reena Priya, J. Mary Linet, Growth, structural, mechanical, optical, and thermal properties of Guanidinium salicylate (GuS) Single crystal for NLO applications, J. Mater. Sci: Mater. Electron., 31, 8144 (2020); https://doi.org/10.1007/s10854-020-03265-2.

T. Arumanayagam, P. Murugakoothan, Studies on growth, spectral and mechanical properties of new organic NLO crystal: Guanidinium 4-nitrobenzoate (GuNB),J. Cryst. Growth, 362, 304 (2013); https://doi.org/10.1016/j.jcrysgro.2011.10.063.

K. Russel Raj, P. Murugakoothan, Growth and physical properties of a new crystal for NLO applications: Bisguanidinium hydrogen phosphate monohydrate (G2HP),J. Cryst. Growth, 362, 130 (2013); https://doi.org/10.1016/j.jcrysgro.2012.01.006.

G. M. Sheldrick, A short history of SHELX, Acta. Cryst. A64, 112 (2008); https://doi.org/10.1107/S0108767307043930.

P. Ramasamy, B. Sridhar, V. Ramakrishnan, R. K. Rajaram, Bis(DL-me¬thioninium) sulfate, Acta. Cryst., E60, 1691 (2004); https://doi.org/10.1107/S1600536804021324.

N. Tiagu, V. Ciupinaa, Prodana, G. I. Rusub, C. Gheorghies, E. J. Vasilec, Influence of Thermal Annealing in Air on the Structural and Optical Properties of Amorphous Antimony Trisulfide Thin Films, J. Optoelectron, Adv. Mater. 6, 211 (2004).

A. K. Chawla, D. Kaur, R, Chandra, Structural and optical characterization of ZnO nanocrystalline films deposited by sputtering, Opt. Mater. 29, 995 (2007); https://doi.org/10.1016/j.optmat.2006.02.020.

D. Kalaivani, S. Vijayalakshmi, J. E. M. Theras, D. Jayaraman, V. Joseph, Growth of L-ValiniumAluminium Chloride single crystal for OLED and super-capacitor applications, Opt. Mat. 50, 87 (2015); https://doi.org/10.1016/j.optmat.2015.09.034.

G. C. Bhar, A. K. Chaudhury, P. Kumbhakar, Study of laser induced damage threshold and effect of inclusions in some nonlinear crystals, Appl. Surf. Sci., 161 (2000); https://doi.org/10.1016/S0169-4332(00)00276-2.

S. A. M. B. Dhas, S. Natrajan, Growth and characterization of L-prolinium tartrate – A new organic NLO material, Cryst. Res. Technol, 42, 471 (2007); https://doi.org/10.1002/crat.200610850.

K, E. Reickhoff, W. L. Peticolas, Optical second-harmonic generation in crystalline amino acids, Science, 147, 610 (1965); https://doi.org/10.1126/science.147.3658.610.

M. Loganayaki, V. Siva Shankar, P. Ramesh, M. N. Ponnuswamy, P. Murugakoothan, Growth and Characterization of Guanidinium Trifluoroacetate – Second Harmonic Generation from a Centrosymmetric Crystal, Journal of Minerals & Materials Characterization & Engineering, 10, 843-853 (2011); https://doi.org/10.4236/jmmce.2011.109065.

Downloads

Published

2024-05-20

How to Cite

Sreedevi, R., Sinthiya, A. S. I. J., Durai, S. C. V., Balu, T., & Murugakoothan, P. (2024). Structural, Growth and Optical Characterization of Guanidinium Sulphanilate (GSA) Single Crystal. Physics and Chemistry of Solid State, 25(2), 278–283. https://doi.org/10.15330/pcss.25.2.278-283

Issue

Section

Scientific articles (Physics)