(Cd)SO4 doping on L-Valine crystal for the enhancement  of opto-electronic and laser properties

G. Susithra; D. Vidhya; S. Ramalingam

doi:10.15330/pcss.25.3.570-578

Authors

G. Susithra AVC College, Mayiladuthurai, Tamilnadu, India
D. Vidhya AVC College, Mayiladuthurai, Tamilnadu, India
S. Ramalingam AVC College, Mayiladuthurai, Tamilnadu, India

DOI:

https://doi.org/10.15330/pcss.25.3.570-578

Keywords:

CdSO4, birefringence, susceptibility, non linear refractive index, EDAX

Abstract

L-Valine is a good molecular platform to induce NLO properties for Laser application and considerable laser properties can be improved by injecting suitable electron administrated substitutional groups. This work is an attempt to make laser properties enhancement by increasing Cd solvent concentration on L-Valine compound. The recorded XRD peaks addressed the significant increment of laser properties of the composite crystal. The results obtained for pure L-Valine was; a=5.221 (Å), b=6.910 (Å) and c=4.994 (Å) and associated indices of refraction was n₁=1.511, n₂=1.583 and n₃=1.599. The results of 2% CdSO₄; a=5.580 (Å), b=7.011 (Å) and c=5.091 (Å) and associated indices of refraction was n₁=1.561, n₂=1.612 and n₃=1.633. For 5% CdSO₄; a=5.599 (Å), b=7.831 (Å) and c=5.659 (Å) and associated indices of refraction was n₁=1.588, n₂=1.661 and n₃=1.699. For 10 % CdSO₄; a=5.592 (Å), b=7.612 (Å) and c=5.822 (Å) and associated indices of refraction was n₁=1.661, n₂=1.693 and n₃=1.593. For 15 % CdSO₄; a=5.551 (Å), b=6.332 (Å) and c=4.734 (Å) and associated indices of refraction was n₁=1.501, n₂=1.599 and n₃=1.593. The non linear refractive index was changed from 3.891 X 10^-8 cm²/W to 4.231 X 10^-8 cm²/W for 2%, 5%, 10% respectively and Third order non linear optical susceptibility (χ⁽³⁾) was ranged from 4.621X10^‑6 esu to 5.091X10^‑6 esu. The restored chemical potential for non linear optical (NLO) and birefringence properties was found to be improved. The scattering capability of homo nuclear and hetero nuclear bonds along with the CdSO₄ voids was identified for attaining non linear scattering process.

References

R.K. Gupta, R.A. Sing, S.S. Dubey, Removal of mercury ions from aqueous solutions by composite of polyaniline with polystyrene, Separation and Purification Technology, 38(3), (2004); https://doi.org/10.1016/j.seppur.2003.11.009.

H.A. Hashem, M.S. Refat, The synthesis and characterization of Rhodamine 6G CT-complexes of iodine, Surf. Rev. Lett. 13, 439 (2006); https://doi.org/10.1142/S0218625X06008414 .

A. Shanthi, C. Krishnan, P. Selvarajan, Studies on growth and characterization of a novel nonlinear optical and ferroelectric material – N,N-dimethylurea picrate single crystal, Journal of Crystal Growth 393, 7 (2014); https://doi.org/10.1016/j.jcrysgro.2013.12.011.

G.F. Jasmine, M. Amalanathan, S.D.D. Roy, Molecular structure and charge transfer contributions to nonlinear optical property of 2-Methyl-4-nitroaniline: A DFT study, J. Mol. Struct. 1112, 63 (2016); https://doi.org/10.1016/j.molstruc.2016.02.013.

X. Zheng, B. Jia, X. Chen, M. Gu, In Situ Third-Order Non-linear Responses During Laser Reduction of Graphene Oxide Thin Films Towards On-Chip Non-linear Photonic Devices, Adv. Mater. 26, 2699 (2014); https://doi.org/10.1002/adma.201304681.

Said Figueredo Lopez, Manuel Paez Meza, Francisco Torres Hoyos, Study of the nonlinear optical properties of 4-nitroaniline type compounds by density functional theory calculations: Towards new NLO materials, Computational and Theoretical Chemistry, 1133, 25 (2018); https://doi.org/10.1016/j.comptc.2018.04.016.

B. Sivasankari, S. Mohana Roopan, L-Malic acid-doped Guanidinium Carbonate crystal: A New NLO Material and its photoluminescence study, Optik - International Journal for Light and Electron Optics, 226, 165909 (2021); https://doi.org/10.1016/j.ijleo.2020.165909.

A. Jagadesan, N. Sivakumar, S. Arjunan, G. Parthipan, Growth, structural, optical, thermal and dielectric behaviour of a novel organic nonlinear optical (NLO) material: Benzimidazolium trichloroacetate monohydrate, Optical Materials, 109, 110285 (2020); https://doi.org/10.1016/j.optmat.2020.110285.

V. Kakekochi, P. Nikhil P, K. Chandrasekharan, U. Kumar D, Impact of donor–acceptor alternation on optical power limiting behavior of H–Shaped thiophene–imidazo[2,1-b] [1,3,4]thiadiazole flanked conjugated oligomers, Dyes and Pigments, 175, 108181 (2020); https://doi.org/10.1016/j.dyepig.2019.108181.

P. Saminathan, M. Senthil Kumar, S. Shanmugan, P. Selvaraju, B. Janarthanan, Kishor Kumar Sadasivuni, Synthesis and characterization of crystalline perfection on L-Lysine co-doping glycine barium chloride/C6H14N2O2 (L-LGBCAC) single crystal for NLO materials, Materials Today: Proceedings 30,57 (2020); https://doi.org/10.1016/j.matpr.2020.04.496.

K.Sankar, R.Rajasekaran, V.Vetrivelan, Synthesis, Growth and Characterization of a Non-Linear Optical Crystal: Glycine Lead acetate (GLA), Materials Today: Proceedings 8, 33(2019); https://doi.org/10.1016/j.matpr.2021.06.258.

H.Q. Sun, D.R. Yuan, X.Q. Wang, Y.Q. Lu, Z.H. Sun, X.C. Wei, X.L. Duan, C.N. Luan, M.K. Lu, D. Xu, Growth and thermal properties of tri-allylthiourea cadmium chloride (ATCC) crystal, J. Cryst. Growth, 256, 183 (2003); https://doi.org/10.1016/S0022-0248(03)01344-7.

S. Senthilkumar, M. Akila, S. Chidambaram, R. Manimekalai, Optical, thermal and mechanical properties of a novel bio-organic chlorophyll-b of Ficus religiosa added nickel sulphate hexahydrate crystal for NLO applications, Chem. Phy. Lett., 754, 137607 (2020); https://doi.org/10.1016/j.cplett.2020.137607.

A.S. Hassanien, Alaa A. Akl, Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films, Superlattices and Microstructures, 89, 153(2016); https://doi.org/10.1016/j.spmi.2015.10.044.