Concentration effects in multicomponent metallic solid solutions

Authors

  • S.I. Protsenko Sumy State University Sumy, Ukraine
  • L.V. Odnodvorets Sumy State University Sumy, Ukraine
  • N.I. Shumakova Sumy State University, Sumy, Ukraine
  • O.O. Pasko Sumy State University Sumy, Ukraine
  • I.Yu. Protsenko Sumy State University Sumy, Ukraine

DOI:

https://doi.org/10.15330/pcss.25.2.284-288

Keywords:

Lattice parameter, Debye temperature, Multicomponent and high-entropy solid solution, Equiatomic approximation, Concentration coefficients

Abstract

In the equiatomic approximation, the dependence of the lattice FCC parameter and the Debye temperature from the atomic fate x of the doping element, which is alternately represented by all elements of a multicomponent solid solution, including high-entropy alloys were obtained. The calculations were carried out on the example of a five-component (based on Cu, Ni, Co, Fe, and Al) or six-component (based on Cu, Ni, Co, Fe, and Cr, Ti) metal systems. It was found that by varying x within x = (0 - 0.3), it is possible to obtain a change in the lattice FCC parameter from 0 to 0.03 nm and the Debye temperatures from 0 to 80 K. The proposed new characteristics are integral and differential concentration coefficients, the magnitude and sign of which can predict concentration dependences for the lattice parameter and the Debye temperature.

References

Yiping Lu, Yong Dong, Li Jiang, Tongmin Wang, Tingju Li, Yong Zhang, Criterion for topological close-packed phase formation in high-entrony alloys, Entropy 17, 2355 (2015); https://doi.org/10.3390/e17042355.

Y. Zhang, X. Yang, P.K. Liaw, Alloy design and properties optimization of high-entropy alloys, JOM 64,830 (2012); https://doi.org/10.1007/s11837-012-0366-5.

A.B. Melnick, V.K. Soolshnenko, K.H. Levchuk, Termodinamic prediction of phase composition of transition metals high-entropy alloys, Metallophysics and Advanced Technologies 42(10), 1387(2020); https://doi.org/10.15407/mfint.42.10.1387.

I. Yu. Protsenko, On the possibility of applying the principle of physical quantities additivity of multicomponent metallic materials, J. Nano- Electron. Phys. 15 (5), 05011 (2023); https://doi.org/10.21272/jnep.15(5).05011.

Yu. S. Bereznyak, L.V.Odnodvorets, N.I. Shumakova, I.Yu. Protsenko, Thermal coefficient of resistance of high-entropy film alloys, IEEE 8-th International Conference of Nanomaterials: Application & Properties, NAP-2018, 19210930 (2018); https://doi.org/10.1109/NAP.2018.8915319.

Yu. Bereznyak, L.V.Odnodvorets, D. Poduremne, I.Yu. Protsenko, A. Rylova, N.I. Shumakova, The Phase Composition of Film Materials with Different Degrees of Entropy, IEEE 9-th International Conference of Nanomaterials: Application & Properties, NAP-2019 (2019). https://ieeexplore.ieee.org/xpl/conhome/9067832/proceeding.

Ming-Hung Tsai, Physical Properties of High Entropy Alloys, Entropy 15, 5338 (2013); https://doi.org/10.3390/e15125338.

Xue Hui Yan, Jin Shan Li, Wei Ran Zhang, Yong Zhang, A brief review of high-entropy films, Materials Chemistry and Physics, Vol. 210, 12 (2018);. https://doi.org/10.1021/acsomega.3c07721.

L.V. Odnodvorets, I.Yu. Protsenko,Y.M. Shabelnyk, N.I. Shumakova, Correlation between the entropy degree and properties of multi-component (high-entropy) film materials, J. Nano- Electron. Phys. 12 (2), 02014 (2020); https://doi.org/10.21272/jnep.12(2).02014.

I.Yu. Protsenko, L.V. Odnodvorets, M.V. Vasyukhno, V.S. Klochok, A.K. Rylova, N.I. Shumakova, Concentration Effects in the Electronic Properties of High- entropy Film Alloys, , J. Nano- Electron. Phys. 14 (4), 04021 (2022); https://doi.org/10.21272/jnep.14(4).04021.

Fizika tverdoho tela. Enciklopedicheskii slovar. Vol. 1 (Ed. by Bar'yakhtar V.G.) – Kyiv: Naukova dumka, 1996. – 656 p. [in Russian].

Fizika tverdoho tela. Enciklopedicheskii slovar. Vol. 2 (Ed. by Bar'yakhtarV.G.) – Kyiv: Naukova dumka, 1998. – 644 p. [in Russian].

Downloads

Published

2024-05-28

How to Cite

Protsenko, S., Odnodvorets, L., Shumakova, N., Pasko, O., & Protsenko, I. (2024). Concentration effects in multicomponent metallic solid solutions. Physics and Chemistry of Solid State, 25(2), 284–288. https://doi.org/10.15330/pcss.25.2.284-288

Issue

Section

Scientific articles (Physics)

Most read articles by the same author(s)