A structural and mechanical study of the maintenance of archaeological Al-brass alloy by simulation method

Authors

  • Omar F. Abdullah Physics Department, College of Education, Samarra University, Samarra, Iraq
  • Orass A. Hussein Physics Department, College of Education, Samarra University, Samarra, Iraq
  • Marwan Al-Lattouf Physics Department, College of Education, Samarra University, Samarra, Iraq
  • Salih Y. Darweesh Physics Department, College of Science, Tikrit University, Tikrit, Iraq

DOI:

https://doi.org/10.15330/pcss.26.4.935-940

Keywords:

Mechanical properties, archaeological Al-brass alloy, simulation method

Abstract

The purpose of this research is to investigate the casting process of producing Al-brass alloy (76% Cu, 22% Zn, 2% Al) and destroying it chemically in accordance with the methods used in simulating damaged archaeological samples; this was achieved by immersing the alloy in a dilute solution of sulfuric acid (H2SO4) with a concentration of 8% molar for 24 hours. This was followed by treatment with a 300 mJ, Nd: YAG laser for 10 seconds at 100 cm, leading to the four stages of the alloy. The damaged alloy had the lowest levels of structural properties with a low hardness value, as opposed to the laser-treated alloy, which had the best structural properties. The results of X-ray diffraction and microscopic imaging by an atomic force microscope and hardness values show that this method is the best way to maintenance.

References

Georges Tsoucaris, and Janusz Lipkowski, eds. Molecular and Structural Archaeology: cosmetic and therapeutic chemicals. Springer Science & Business Media, 117, (2003); https://doi.org/10.1007/978-94-010-0193-9.

Meeks, Nigel. Surface characterization of tinned bronze, high-tin bronze, tinned iron and arsenical bronze. Metal plating and patination. Butterworth-Heinemann, 247 (1993); https://doi.org/10.1016/B978-0-7506-1611-9.50025-X

Ahmad Abu-Baker, Analytical investigation and electrochemical conservation treatment for archaeological copper alloy artifacts from Jordan. Conservar Património? 42, 38 (2023); https://doi.org/10.14568/cp26263.

Karim, A. S., Majeed, Z. N., & Darweesh, S. Y. (2021, August). The effect of nanostructured zirconia reinforcement on the mechanical and structural properties of a copper-based system. In Materials Science Forum (Vol. 1039, pp. 297-306). Trans Tech Publications Ltd.‏ https://doi.org/10.4028/www.scientific.net/MSF.1039.297.

Hussein, Orass A., Omar F. Abdullah, and Sara S. Tawfeek. Determination of physical and thermal properties of Triiodosilane by semi-empirical approach. Iraqi Journal of Applied Physics, 20(2B), 449 (2024); https://doi.org/10.2025/ae14kr35.

Smallman, Raymond E., and A. H. W. Ngan. Physical metallurgy and advanced materials. Elsevier, 2011.‏

M. Mereu, V. Basilissi, G. Guida, M. Vidale, M.P. Casaletto, G.M. Ingo, ... & E. Greco, Conservation of copper alloys artefacts from archaeological excavation. YOCOCU: Contribute and Role of Youth in Conservation of Cultural Heritage, 163 (2011); https://doi.org/10.13140/2.1.2424.3525.

Ahmed, M. N., Daham, N. A., & Darweesh, S. Y. (2024, February). Structural and mechanical properties for (Ni-WC) system by using thermal spray. In AIP Conference Proceedings (Vol. 2885, No. 1, p. 020013). AIP Publishing LLC.‏ https://doi.org/10.1063/5.0181722.

T. Giraud, A. Gomez, S. Lemoine, C. Pelé-Meziani, A. Raimon, & E. Guilminot, Use of gels for the cleaning of archaeological metals. Case study of silver-plated copper alloy coins. Journal of Cultural Heritage 52, 73 (2021); https://doi.org/10.1016/j.culher.2021.08.014.

Al-Qaseer, Ahmed Laftah Rahma. The technique of manufacturing metal alloys as a model for the development of chemistry in the civilization of Mesopotamia in the light of Cuneiform texts and archaeological evidence. Iraqi Journal of Humanitarian, Social and Scientific Research, 3 (9S), 100 (2023).‏

Bolton, William. Engineering materials technology. Elsevier, 2013.‏

Raghavan, Viswanatha. Materials Science and Engineering: A first course. PHI Learning Pvt. Ltd., 2015.‏

Hofmann, Philip. Solid state physics: an introduction. John Wiley & Sons, 2022.‏

A.V. Feitosa, et al. A new route for preparing CdS thin films by chemical bath deposition using EDTA as ligand. Brazilian Journal of Physics, 34, 656 (2004); https://doi.org/10.1590/S0103-97332004000400034.

William Bolton. Engineering materials technology. Elsevier, 2013.‏

I.K. Jassim, K.H. Erzaich, M.A. Majeed, & O.F. Abdullah, The effect of heat treatment on the structural properties of the (Alnico-5) alloy prepared by powder metallurgy method. Advances in Applied Science Research, 36‏ (2015).

R. S.Antar, S. Y.Darweesh, & F. W.Ridha, Production of a double cermet coating to treatment of the turbine blades. Engineering Research Express, 6(1), 015407 (2024);‏ https://doi.org/10.1088/2631-8695/ad2f82.

‏Huba, Zachary John. Synthesis and characterization of cobalt carbide based nanomaterials. Virginia Commonwealth University, 2014.‏

S. Baek, S. Choi, J.O. Kim, Y.J. Kim, & C. Park, Effect of laser surface cleaning on yellow brass: Application for cartridge case maintenance. Optics & Laser Technology, 174, 110638. (2024); https://doi.org/10.1016/j.optlastec.2024.110638.

Salih, W. A., Allah, S. M. A., & Darweesh, S. Y.. Effect of spray angle on some physical properties of a ceramic system produced by thermal spraying coating. Al-Bahir Journal for Engineering and Pure Sciences, 2(2), 4 (2023);‏ https://doi.org/10.55810/2313-0083.1022.

Downloads

Published

2025-12-26

How to Cite

Abdullah, O. F., Hussein, O. A., Al-Lattouf, M., & Darweesh, S. Y. (2025). A structural and mechanical study of the maintenance of archaeological Al-brass alloy by simulation method. Physics and Chemistry of Solid State, 26(4), 935–940. https://doi.org/10.15330/pcss.26.4.935-940

Issue

Section

Scientific articles (Physics)