Application of Ar⁺ion implantation for obtaining nanocontacts on the GaP (111) single crystals surface
DOI:
https://doi.org/10.15330/pcss.27.1.983-987Keywords:
GaP(111), Ion implantation Ar⁺, Ohmic contact, metal–semiconductor interfaceAbstract
Ultrathin ohmic contacts were fabricated on GaP(111) single crystals using argon ion (Ar⁺) implantation at an energy of E₀ = 2 keV and a dose of D = 2 × 10¹⁷ cm⁻², under high vacuum conditions (10⁻⁷ Pa). Post-irradiation analysis revealed a significant enrichment of the surface with gallium, reaching a concentration of approximately 90 at.%. Subsequently, a nickel (Ni) film with a thickness of about 1000 Å was deposited onto the GaP(111) surface to form the contact. This metallization step led to a three- to fourfold reduction in the total thickness of the contact layer compared to conventional approaches. Upon thermal treatment at T = 850 K, the initially disordered GaP(111) layers recrystallized, resulting in a polycrystalline contact structure. After annealing, the thickness of the contact layer increased by approximately 1.5 times, reaching 400–450 Å, which is still around 2.5 times thinner than the characteristic thickness (dₙ) in the Ni/pure-GaP system. These findings demonstrate that ion implantation, followed by controlled metallization and annealing, provides an effective route for producing ultrathin, thermally stable ohmic contacts for GaP-based semiconductor devices.
References
S. Laref, S. Meçabih, B. Abbar, B. Bouhafs, A. Laref, First-principle calculations of electronic and positronic properties of AlGaAs2, Physica B: Condensed Matter, 396 (1-2), 169 (2007); https://doi.org/10.1016/j.physb.2007.03.033.
S.B. Donaev, F. Djurabekova, D.A. Tashmukhamedova, B.E. Umirzakov, Formation of nanodimensional structures on surfaces of GaAs and Si by means of ion implantation. Physica Status Solidi (c), 12(1‐2), 89 (2015); https://doi.org/10.1002/pssc.201400156.
B.E. Umirzakov, D.A. Tashmukhamedova, E.U. Boltaev, A.A. Dzhurakhalov, Obtaining of epitaxial films of metal silicides by ion implantation and molecular beam epitaxy. Materials Science and Engineering: B, 101(1-3), 124 (2003); https://doi.org/10.1016/S0921-5107(02)00677-3.
B.E. Umirzakov, D.A. Tashmukhamedova, M.K. Ruzibaeva, F.G. Djurabekova, S.B. Danaev, Investigation of change of the composition and structure of the CaF2/Si films surface at the low-energy implantation. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 326, 322 (2014); https://doi.org/10.1016/j.nimb.2013.10.094.
K.K. Boltaev, D.A. Tashmukhamedova, B.E. Umirzakov, Structure and electronic properties of nanoscale phases and nanofilms of metal silicides produced by ion implantation in combination with annealing. Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques, 8(2), 326 (2014); https://doi.org/10.1134/S1027451014010108.
S. Donaev, G. Shirinov, B. Umirzakov, B. Donayev, S. Wang, Effect of Low-Energy Implantation of In+ Ions on the Composition and Electronic Structure of Single-Crystal GaP (111), Coatings, 14(10), 1231 (2024); https://doi.org/10.3390/coatings14101231.
T.S. Kamilov, A.S. Rysbaev, V.V. Klechkovskaya, A.S. Orekhov, B.D. Igamov, I.R. Bekpulatov, The influence of structural defects in silicon on the formation of photosensitive Mn4Si7–Si❬ Mn❭–Mn4Si7 and Mn4Si7–Si❬Mn❭–M heterostructures. Applied Solar Energy, 55(6), 380 (2019); https://doi.org/10.3103/S0003701X19060057.
S.B. Donaev, A.K. Tashatov, B.E. Umirzakov, Effect of Ar+-ion implantation on the composition and structure of the surface of CoSi2/Si (111) nanofilms. Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques, 9(2), 406 (2015); https://doi.org/10.1134/S1027451015020263.
N.M. Mustafoeva, A.K. Tashatov, B.E. Umirzakov, M.B. Mamatova, On Si/NiSi2/Si (111) Heterostructures Obtained by Solid-Phase Deposition. Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques, 18(6), 1415 (2024); https://doi.org/10.1134/S1027451024701337.
S.M. Hong, Y.S. Kim, H.S. Min, Y.J. Park, Characteristic potential method of noise calculation in semiconductor devices: calculation of 1/f noise in MOS transistors in the ohmic region. In Noise in Devices and Circuits, (5113), 267 (2003); https://doi.org/10.1117/12.488947.
M. Rizzo Piton, T. Hakkarainen, J. Hilska, E. Koivusalo, D. Lupo, H. V. A. Galeti, M. Guina. Optimization of Ohmic Contacts to p-GaAs Nanowires. Nanoscale Research Letters, 14(1), 344 (2019); https://doi.org/10.1186/s11671-019-3175-8.
R.R. LaPierre, M. Robson, K.M. Azizur-Rahman, P. Kuyanov. A review of III–V nanowire infrared photodetectors and sensors. Journal of Physics D: Applied Physics, 50(12), 123001 (2017); https://doi.org 10.1088/1361-6463/aa5ab3.
T.V. Hakkarainen, A. Schramm, J. Mäkelä, P. Laukkanen, M. Guina, Lithography-free oxide patterns as templates for self-catalyzed growth of highly uniform GaAs nanowires on Si (111), Nanotechnology, 26(27), 275301 (2015); https://doi.org 10.1088/0957-4484/26/27/275301.
H. Kawaura, T. Sakamoto, T. Baba, Observation of source-to-drain direct tunneling current in 8 nm gate electrically variable shallow junction metal–oxide–semiconductor field-effect transistors. Applied Physics Letters, 76(25), 3810 (2000); https://doi.org/10.1063/1.126789.
D. Lizzit, P. Khakbaz, F. Driussi, M. Pala, D. Esseni, Ohmic behavior in metal contacts to n/p-type transition-metal dichalcogenides: Schottky versus tunneling barrier trade-off. ACS Applied Nano Materials, 6(7), 5737 (2023); https://doi.org/10.1021/acsanm.3c00166.
B.E. Umirzakov, T.S. Pugacheva, A.T. Tashatov, D.A. Tashmukhamedova, Electronic structure and optical properties of CaF2 films under low energy Ba+ ion-implantation combined with annealing. Nuclear instruments & methods in physics research section B-beam interactions with materials and atoms, 166-167, 572 (2000); https://doi.org/10.1016/S0168-583X(99)01151-9.
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Copyright (c) 2026 Baltokhodzha Ermatovich Umirzakov , Sardor Burkhonovich Donaev , Ganjimurod Mamir ugli Shirinov, Rashad Abaszade

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