Effect of Al, Fe Addition on Thermodynamic Stability and Hydrogen Desorption KInetics from MgH2 Phase OF Mechanical Alloy

Authors

  • О.G. Еrshova Frantsevich Institute for Problems of Materials Science
  • A.Yu. Koval Frantsevich Institute for Problems of Materials Science
  • Yu.М. Solonin Frantsevich Institute for Problems of Materials Science
  • V.D. Dobrovolsky Frantsevich Institute for Problems of Materials Science

DOI:

https://doi.org/10.15330/pcss.16.3.576-585

Keywords:

hydride phase, thermal stability, kinetics, thermal desorption spectroscopy

Abstract

With the aim of lowering the temperature, improve the kinetics of the decomposition of stoichiometric hydride MgH2 was investigated the possibility of its complex doping Al, Fe using mechanochemical synthesis (RMS). The MA1 sample was derived by reactive milling  Mg + 10 wt% Al + 10 wt. % Fe powder mixture in the hydrogen atmosphere at pressure of 1.2 MPa in a reactor for 10 h. The formation (in conditions of mechanochemical synthesis) of hydride of solid solution of Al and Fe in magnesium Mg(Al,Fe)H2 was experimentally checked. Found that adding to magnesium Al & Fe leads to lower of thermodynamic stability and, consequently, to lower the temperature of the beginning of desorption of hydrogen to 250 0C at 0,1MPa H2 (compared to MgH2 without Al and Fe). After the first cycles of hydrogenation-dehydrogenation from gas phase MA, established by isobaric thermal desorption spectroscopy, the effect of lowering the temperature of the beginning desorbtion 315 0C (for non-alloy phase MgH2) to 250 0C was observed. Adding to magnesium aluminum with Fe significantly improves the kinetics of desorption of hydrogen from the hydride phase MgH2 mechanical alloy produced by RMS.

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Published

2015-09-15

How to Cite

Еrshova О., Koval, A., Solonin, Y., & Dobrovolsky, V. (2015). Effect of Al, Fe Addition on Thermodynamic Stability and Hydrogen Desorption KInetics from MgH2 Phase OF Mechanical Alloy. Physics and Chemistry of Solid State, 16(3), 576–585. https://doi.org/10.15330/pcss.16.3.576-585

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Section

Scientific articles