Nonlinear features of the transition of a liquid crystalline mixture into an isotropic state under the action of alcohol vapors
DOI:
https://doi.org/10.15330/pcss.24.1.64-69Keywords:
optical sensor, E7, alcohols vapor, CB15Abstract
The work of an optical sensor for determining the concentration of alcohols, in particular methanol, ethanol and isopropanol, based on a liquid crystal sensitive element, was studied. The sensitive element is a mixture of cholesteric liquid crystal CB15 and nematic impurity E7. The detection and reaction of the sensitive element to the presence of alcohol vapors is investigated.
References
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26 Gurboga B., Kemiklioglu E. Optical sensing of organic vapor using blue phase liquid crystals. Liq.Cryst., 2022, v.49, No.11, p.1428-1435.
2 Ding, Xiaokang, and Kun-Lin Yang. "Liquid crystal based optical sensor for detection of vaporous butylamine in air." Sensors and Actuators B: Chemical 173 (2012): 607-613.
3 Aksimentyeva, O., Mykytyuk, Z., Fechan, A., Sushynskyy, O., & Tsizh, B. (2014). Cholesteric liquid crystal doped by nanosize magnetite as an active medium of optical gas sensor. Molecular Crystals and Liquid Crystals, 589(1), 83-89.
4 Rusyn, I., & Bataller, R. (2013). Alcohol and toxicity. Journal of hepatology, 59(2), 387-388.
5 Hayreh, M. S., Hayreh, S. S., Baumbach, G. L., Cancilla, P., Martin-Amat, G., Tephly, T. R., ... & Makar, A. B. (1977). Methyl alcohol poisoning: III. Ocular toxicity. Archives of Ophthalmology, 95(10), 1851-1858.
6 Karasek, F. W., Cohen, M. J., & Carroll, D. I. (1971). Trace studies of alcohols in the plasma chromatograph—mass spectrometer. Journal of Chromatographic science, 9(7), 390-392.
7 Quirke, J. M. E., Adams, C. L., & Van Berkel, G. J. (1994). Chemical derivatization for electrospray ionization mass spectrometry. 1. Alkyl halides, alcohols, phenols, thiols, and amines. Analytical chemistry, 66(8), 1302-1315.
8 Peláez, J., & Wilson, M. (2007). Molecular orientational and dipolar correlation in the liquid crystal mixture E7: a molecular dynamics simulation study at a fully atomistic level. Physical Chemistry Chemical Physics, 9(23), 2968-2975.
9 Mykytiuk, Z., Barylo, H., Kremer, I., Ivakh, M., Kachurak, Y., & Kogut, I. (2022). Features of the transition to the isotropic state of the liquid crystal sensitive element of the gas sensor under the action of acetone vapor. Physics and Chemistry of Solid State, 23(3), 473-477.
10 Chapman, O. L., & King, R. W. (1964). Classification of alcohols by nuclear magnetic resonance spectroscopy. Journal of the American Chemical Society, 86(6), 1256-1258.
11 Bradley, R. J. (2000). Chemical properties of alcohols and their protein binding sites. Cellular and Molecular Life Sciences CMLS, 57(2), 265-275.
12 Rizk, H. A., & Elanwar, I. M. (1968). Dipole moments of glycerol, isopropyl alcohol, and isobutyl alcohol. Canadian Journal of Chemistry, 46(4), 507-513.
13 Jorge, M., Gomes, J. R., & Barrera, M. C. (2022). The dipole moment of alcohols in the liquid phase and in solution. Journal of Molecular Liquids, 356, 119033.
14 O'Keefe, G. E., De Mello, J. C., Denton, G. J., McEwan, K. J., & Till, S. J. (1996). Transient excited-state absorption of the liquid crystal CB15 [4-(2-methylbutyl)-4-cyanobiphenyl] in its isotropic phase. Liquid crystals, 21(2), 225-232.
15 Lonhin, L. (2009). Liquid crystals as sensory and bioequivalent materials. Monograph, Kh.: ISMA.
16 Singh, S. (2000). Phase transitions in liquid crystals. Physics Reports, 324(2-4), 107-269.
17 Fan, C. P., & Stephen, M. J. (1970). Isotropic-nematic phase transition in liquid crystals. Physical Review Letters, 25(8), 500.
18 Stephen, M. J., & Straley, J. P. (1974). Physics of liquid crystals. Reviews of Modern Physics, 46(4), 617.
19 Sushynskyi, O.,Vistak, M., Dmytrah,V. (2016). The sensetive element of primary transduser of protein optical sensorModern Problems of Radio Engineering,Telecomunications and Computer Scence, Proceetings of the 13 International Conference on TCSET 2016, art.no.7452075,418-421.
20 Wojcik, W., Mykytyuk, Z., Vistak,M., Barylo,G., Politanskyi, R., Diskovskyi,I., Kremer,I., Ivakh,M., Kotsun,W. (2020), Optical sensor with liquid crystal sensetive element for amino asids detection. Przeglad Elektrotechniczny,96(4),178-181.
21 Vistak, M., Dmytrah, V., Fafula, R., Diskovskyi, I., Mykytyuk, Z., Sushynskyi, O., ... & Horbenko, Y. (2017, September). Liquid crystals as an active medium of enzymes optical sensors. In 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP) (pp. 04NB13-1). IEEE.
22 TCS34903FN Datasheet https://media.ncd.io/sites/2/20170721134410/AMS_TCS3490_Datasheet_1v02-516236.pdf
23 Gvozdovskyy I.A. ‘Blue phases’ of highly chiral thermotropic liquid crystals with a wide range of near-room temperature. Liq.Cryst., 2015, v.42, No.10, p.1391-1404.
24 Johnson DL, Flack JH, Crooker PP. Structure and properties of the cholesteric blue phases. Phys Rev Lett. 1980, v.45, p.641–644.
25 Asiqur Rahman M.D., Mohd Said S., Balamurugan S. Blue phase liquid crystal: strategies for phase stabilization and device development. Sci.Technol.Adv.Mater., 2015, v.16, No.3, 033501-1-21.
26 Gurboga B., Kemiklioglu E. Optical sensing of organic vapor using blue phase liquid crystals. Liq.Cryst., 2022, v.49, No.11, p.1428-1435.
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Published
2023-02-23
How to Cite
Mykytyuk, Z., Barylo, H., Kremer, I., Kachurak, Y., Samoilov, O., & Kogut, I. (2023). Nonlinear features of the transition of a liquid crystalline mixture into an isotropic state under the action of alcohol vapors. Physics and Chemistry of Solid State, 24(1), 64–69. https://doi.org/10.15330/pcss.24.1.64-69
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Scientific articles (Technology)
