A Fractal Approach to Evaluating the Thermal Conductivity of ZrB2–C Composite Ceramic Materials
DOI:
https://doi.org/10.15330/pcss.27.1.52-61Keywords:
ceramic composites, boron carbide, zirconium carbide, zirconium diboride, graphite, microstructure, fractal analysis, thermal conductivity, lacunarity, energy industryAbstract
A pressing issue in materials science is the controlled application of ceramic composite materials at high temperatures in modern technologies, particularly in nuclear physics, atomic energy, aerospace, and rocket engineering. This study investigates the correlation between the thermal conductivity of synthesized ZrB2–C ceramic composites and their microstructural features using fractal analysis. The composites were produced via high-temperature reactive synthesis from boron and zirconium carbide powders. Scanning electron microscopy (SEM) and backscattered electron (BSE) modes was used to obtain micrographs of the fracture surfaces. These images were analyzed using the Box Counting method with ImageJ and FracLac software to determine two fractal parameters: fractal dimension and lacunarity. A strong inverse correlation was observed between lacunarity and thermal conductivity. The study demonstrates that fractal analysis, particularly the lacunarity parameter, can serve as a useful tool for assessing heat transfer potential in two-phase ceramic composites, especially when conventional measurement methods are impractical.
References
A. Khomenko, E Khomenko, G Bagliuk, B Miedzinski, A Kozlowski, Investigation of correlation between physical properties and microstructure geometrical parameters of Cr-Cu composite material used for vacuum arcing contacts, Mining–Informatics, Automation and Electrical Engineering, Kyiv, 54(2), 29 (2016); https://journals.indexcopernicus.com/api/file/viewByFileId/235702.
P. Budanov, E Khomiak, Improving the system for monitoring the tightness of the cladding of the fuel element of a nuclear reactor, Engineering [Mashynobuduvannja], 29, 32 (2022); https://jmash.uipa.edu.ua/index.php/jMASH/article/view/284/208.
M.R.B. Dias, D. Dornelas, W.F. Balthazar, J.A.O. Huguenin, L. da Silva, Lacunarity study of speckle patterns produced by rough surfaces, Physica A: Statistical Mechanics and its Applications, 486, 328 (2017); https://doi.org/10.1016/j.physa.2017.05.022.
A. Karperien, H. Ahammer, H. F. Jelinek, Quantitating the subtleties of microglial morphology with fractal analysis, Frontiers in cellular neuroscience, 7, 3 (2013); https://doi.org/10.3389/fncel.2013.00003.
E.P. Pinto, M.A. Pires, R.S. Matos, R.R. M. Zamora, R.P. Menezes, R.S. Araújo, T.M. de Souza, Lacunarity exponent and Moran index: A complementary methodology to analyze AFM images and its application to chitosan films, Physica A: Statistical Mechanics and its Applications, 581, 126192 (2021); https://doi.org/10.1016/j.physa.2021.126192.
A. Roy, E. Perfect, Lacunarity analyses of multifractal and natural grayscale patterns, Fractals, 22(03), 1440003 (2014); https://doi.org/10.1142/S0218348X14400039.
F. Cervantes-Alvarez, J. J. Reyes-Salgado, V. Dossetti, J. L. Carrillo, Thermal properties of composite materials with a complex fractal structure, J. Phys. D: Appl. Phys., 47, 235303 (2014); https://doi.org/10.1088/0022-3727/47/23/235303.
L. C. Feng, N. Xie, W. Z. Shao, L. X. Lu, L. Zhen, J. Zhao, Thermal conductivity determination of conductor/insulator composites by fractal: Geometrical tortuosity and percolation, Composites Part B: Engineering, 92, 377 (2016); https://doi.org/10.1016/j.compositesb.2016.02.046.
V.V. Usov, M.D. Rabkina, N.M. Shkatuliak, T.S. Cherneva, The fractal dimension of grain boundaries and mechanical properties of the oxygen cylinders metal, Physicochemical Mechanics of Materials, 50(4), 117 (2014); http://nbuv.gov.ua/UJRN/PHKhMM_2014_50_4_19
V. Ivanov, V. Pirozhkova, V. Lunеv, Research of structure and formation of nodular graphite inclusions in ductile cast iron, Eastern-European Journal of Enterprise Technologies, 3(5(81)), 31 (2016); https://journals.uran.ua/eejet/article/view/69674/66776.
D.M. Stefanescu, G. Alonso, P. Larranaga, E. De la Fuente, R. Suarez, On the crystallization of graphite from liquid irone-carbone-silicon melts, Acta Materialia, 107, 102 (2016); https://doi.org/10.1016/j.actamat.2016.01.047.
M. Mróz, A. W. Orłowicz, M. Tupaj, M. Jacek-Burek, M. Radoń, M. Kawiński, The Effect of Structure on Thermal Power of Cast-iron Heat Exchangers, Archives of Foundry engineering, 20(1), 27 (2020); https://doi.org/10.24425/afe.2020.131278.
C. Li, Y. Xu, Z. Jiang, B. Yu, P. Xu. Fractal Analysis on the Mapping Relationship of Conductivity Properties in Porous Material, Fractal and Fractional, 6(9), 527 (2022); https://www.mdpi.com/2504-3110/6/9/527.
Z. Y. Du, M. L. Yang, Q. G. Liu, M. Yu, Numerical investigation on Thermal Conduction in Fractal-like Porous Media, Arch Environ Sci Environ Toxicol: AESET-109 (2019); https://www.gavinpublishers.com/assets/articles_pdf/1553244837article_pdf1275728101.pdf.
W.G. Fahrenholtz, E.J. Wuchina, W.E. Lee, Y. Zhou (Editors), Ultra-High Temperature Ceramics Materials for Extreme Environment Applications, John Wiley & Son, 2014. ISBN:9781118700785 ; https://onlinelibrary.wiley.com/doi/book/10.1002/9781118700853.
A.L. Chamberlain, W.G. Fahrenholtz, G.E. Hilmas, D.T. Ellerby, High-strength zirconium diboride-based ceramics, J. Am. Ceram. Soc., 87(6), 1170 (2004); https://doi.org/10.1111/j.1551-2916.2004.01170.x.
G. J. K. Harrington, G. E. Hilmas, Thermal Conductivity of ZrB2 and HfB2, Ultra-High Temp. Ceram. Mater. Extrem. Environ. Appl., John Wiley & Sons, Ltd, 197 (2014); https://doi.org/10.1002/9781118700853.ch9.
G.R. Peterson, R.E. Carr, E.E. Marinero, Zirconium Carbide for Hypersonic Applications, Opportunities and Challenges, Materials (Basel), 16(18), 6158 (2023); https://doi.org/10.3390/ma16186158.
Yu. Zhao, Yi. Tao, K. Lin, J. Yang, J. Sha, Yu. Chen, Experimental measurement of thermal conductivity along different crystallographic planes in graphite, J. Appl. Phys., 128, 045118 (2020); https://doi.org/10.1063/5.0013474.
C. Wood, D. Emin, P. E. Gray, Thermal conductivity behaviour of boron carbides, Physical Review B, 31(10), 6811 (1985); https://doi.org/10.1103/PhysRevB.31.6811.
F.S. Moghanlou, M. Vajdi, J. Sha, A. Motallebzadeh, M. Shokouhimehr, M. S. Asl, A numerical approach to the heat transfer in monolithic and SiC reinforced HfB2, ZrB2 and TiB2 ceramic cutting tools, Ceram. Int., 45(13), 15892 (2019); https://doi.org/10.1016/j.ceramint.2019.05.095.
O. Popov, J. Vleugels, E. Zeynalov, V. Vishnyakov, Reactive hot pressing route for dense ZrB2-SiC and ZrB2-SiC-CNT ultra-high temperature ceramics, Journal of the European Ceramic Society, 40(15), 5012 (2020); https://doi.org/10.1016/j.jeurceramsoc.2020.07.039.
O. Popov, Thermal conductivity and thermal shock resistance of TiB2-based UHTCs enhanced by graphite platelets, Mater. Today Commun., 26, 101756 (2021); https://doi.org/10.1016/j.mtcomm.2020.101756.
D. Ristanović, N. T. Milosević, Fractal analysis: methodologies for biomedical researchers, Theor Biol Forum, 105(2), 99 (2012); PMID: 23757956; https://pubmed.ncbi.nlm.nih.gov/23757956/
O. Krit, A. Shirinyan, L Marynchenko, O. Nizhelska, Assessment of Changes in the Texture of the Silicon Surface under the Influence of a Magnetic Field and High-Temperature Plastic Deformation Using Fractal Analysis, Him. Fiz. Tehnol. Poverhni, 16 (3), 339 (2025); https://cpts.com.ua/index.php/cpts/article/view/805/804.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 A.S. Shirinyan, L.V. Marynchenko, O.I. Nizhelska

This work is licensed under a Creative Commons Attribution 3.0 Unported License.




