Formation of Interatomic Bonds of the Fumed Synthesis of Composites SiO2+Al2O3

Authors

  • Ya.V. Zaulychnyy Physical Engineering Faculty, National Technical University of Ukraine “Kyiv Polytechnical Institute”
  • М.V. Karpetz Frantsevich Institute for Problems of Materials Science
  • Y.V. Yavorskyi Physical Engineering Faculty, National Technical University of Ukraine “Kyiv Polytechnical Institute”,
  • V.М. Gun'ko Chuiko Institute of Surface Chemistry
  • V.I. Zarko Chuiko Institute of Surface Chemistry
  • V.Ya. lkiv Physical Engineering Faculty, National Technical University of Ukraine “Kyiv Polytechnical Institute”,

DOI:

https://doi.org/10.15330/pcss.16.2.425-431

Keywords:

Al2O3, SiO2, ultra-advanced X-ray spectroscopy, pyrogenic synthesis, radiographic analysis

Abstract

Crystalline and electronic structures of SiO2/Al2O3 mixtures have been analyzed using X-ray diffraction (XRD) and ultra-soft X-ray emission spectroscopy (USXES). Comparison of ultrasoft X-ray emission AlLα-, SiLα- and OKα-bands redistribution Alsp-, Sisp- and Op-valence electrons when changing the mass ratio (0,23Al2O3+0,77 SiO2;, 0,30Al2O3+0,70SiO2; 0,75Al2O3+25 SiO2) and depending on the method of obtaining them. Expansion OKα-emission bands showed an increase in population of Opπ-levels of oxygen in the formation of pyrogenic composites with different contents of aluminum oxide and silicon dioxide. Analysis AlLα-, SiLα- emission bands allowed to explain the increase of population Opπ-levels of oxygen and present the morphology  formation of particles different  of pyrogenic composites during synthesis.

 

References

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Published

2015-06-15

How to Cite

Zaulychnyy, Y., Karpetz М., Yavorskyi, Y., Gun'ko, V., Zarko, V., & lkiv , V. (2015). Formation of Interatomic Bonds of the Fumed Synthesis of Composites SiO2+Al2O3. Physics and Chemistry of Solid State, 16(2), 425–431. https://doi.org/10.15330/pcss.16.2.425-431

Issue

Section

Scientific articles