Ameliorating and Tailoring the Morphological and Optical Properties of PEO-MnO2-SrTiO3 Solid State Nanocomposites  for Electronics Fields

Editorial Board PCSS Journal; М.Х. Аббас; Сайф Х. Хамід; Ахмед Хашим

doi:10.15330/pcss.27.2.263-271

Автор(и)

М.Х. Аббас Університет Вавилону, Коледж освіти з чистих наук, кафедра фізики, Вавилон, Ірак
Сайф Х. Хамід Університет Вавилону, Коледж освіти з чистих наук, кафедра фізики, Вавилон, Ірак
Ахмед Хашим Університет Вавилону, Коледж освіти з чистих наук, кафедра фізики, Вавилон, Ірак

DOI:

https://doi.org/10.15330/pcss.27.2.263-271

Ключові слова:

PEO, нанокомпозити, MnO₂, SrTiO₃, оптичні властивості, ширина забороненої зони

Анотація

У роботі методом лиття отримано плівки полімерних нанокомпозитів PEO–MnO₂–SrTiO₃ з різним масовим вмістом наночастинок (1,7 %, 3,4 % та 5,1 %). Досліджено їх морфологічні та оптичні властивості. Показано, що зі збільшенням концентрації MnO₂–SrTiO₃ поверхня плівок стає більш однорідною та щільною, а оптичні характеристики суттєво покращуються. Встановлено зростання поглинання до 75–76 % у видимому діапазоні спектра та зменшення пропускання з 43 % до 41 % при максимальному вмісті наночастинок. Коефіцієнт поглинання збільшується до 8589 см⁻¹, тоді як ширина забороненої зони для дозволених і заборонених непрямих переходів зменшується відповідно до 3,3 еВ та 3,2 еВ. Оптична провідність зростає з 3,1 × 10¹² с⁻¹ для чистого PEO до 1,6 × 10¹³ с⁻¹ при вмісті наночастинок 5,1 %. Отримані результати свідчать про перспективність використання плівок PEO–MnO₂–SrTiO₃ в оптичних та електронних пристроях.

Посилання

Sun, Chunxia. Controlling the rheology of polymer/silica nanocomposites, (2010).

T.A. Taha, et al. Dielectric spectroscopy of PVA-Ni0.5Zn0.5Fe2O4 polymer nanocomposite films. Journal of Asian Ceramic Societies, 8(4), 1076‏ (2020); https://doi.org/10.1080/21870764.2020.1812839.

Okpala, Charles Chikwendu. Nanocomposites–an overview. International Journal of Engineering Research and Development, 8(11), 17 (2013).

A. Hashim, A. Hadi, & M.H. Abbas, Synthesis and Unraveling the Morphological and Optical Features of PVP-Si3N4-Al2O3 Nanostructures for Optical and Renewable Energies Fields, Silicon 15, 6431 (2023); https://doi.org/10.1007/s12633-023-02529-w.

H.K. Jaafar, A. Hashim, & B.H. Rabee, Fabrication and tuning the morphological and optical characteristics of PMMA/PEO/SiC/BaTiO3 newly quaternary nanostructures for optical and quantum electronics fields. Opt Quant Electron, 55, 989 (2023); https://doi.org/10.1007/s11082-023-05208-7.

Z.M. Elimat, A.M. Zihlif, and Maurizio Avella. Thermal and optical properties of poly (methyl methacrylate)/calcium carbonate nanocomposite. Journal of Experimental Nanoscience, 3(4), 259 (2008); https://doi.org/10.1080/17458080802603715.

Ma, Lulu, Li Deng, and Jianming Chen. Applications of poly (ethylene oxide) in controlled release tablet systems: a review. Drug development and industrial pharmacy, 40 (7), 845 (2014); https://doi.org/10.3109/03639045.2013.831438.

My Ahmed Said Azizi Samir, Fannie Alloin, Jean-Yves Sanchez, Alain Dufresne, Cellulose nanocrystals reinforced poly (oxyethylene). Polymer, 45(12); 4149 (2004); https://doi.org/10.1016/j.polymer.2004.03.094.

M.A.S. Azizi Samir, L. Chazeau, F. Alloin, J.-Y. Cavaillé, A. Dufresne, J.-Y. Sanchez, POE-based nanocomposite polymer electrolytes reinforced with cellulose whiskers. ElectrochimicaActa, 50(19), 3897 (2005); https://doi.org/10.1016/j.electacta.2005.02.065.

H.B. Hassan, A. Hashim, & H.M. Abduljalil, Synthesis, structural and optical characteristics of PEO/NiO/In2O3 hybrid nanomaterials for photodegradation of pollutants from wastewater. Opt Quant Electron, 55, 556 (2023); https://doi.org/10.1007/s11082-023-04830-.

H.B. Hassan, A. Hashim, & H.M. Abduljalil, Tailoring structural, optical characteristics of CuO/In2O3 nanoparticles-doped organic material for photodegradation of dyes pollutants. Polym. Bull., 80, 9059 (2023); https://doi.org/10.1007/s00289-022-04502-w.

AL‐Akhras, M‐Ali, et al. Studies of composite films of polyethylene oxide doped with potassium hexachloroplatinate. Journal of Applied Polymer Science, 138(5), 49757 (2021); https://doi.org/10.1002/app.49757.

Al-Akhras, M. Ali, et al. Optical and chemical investigations of PEO thin films incorporated with curcumin nanoparticle: effect of film thickness. Biointerface Research in Applied Chemistry, 13(2), 143 (2023); https://doi.org/10.33263/BRIAC132.143.

Mishra Rachna, and K. J. Rao. Electrical conductivity studies of poly (ethyleneoxide)-poly (vinylalcohol) blends. Solid State Ionics, 106(1-2), 113 (1998); https://doi.org/10.1016/S0167-2738(97)00493-1.

A. Kareem, A. Hashim, & H.B. Hassan, Synthesis and Boosting the Morphological, Structural and Optical Features of PEO/Si3N4/CeO2 Promising Nanocomposites Films for Futuristic Nanoelectronics Applications. Silicon, 16, 2827 (2024); https://doi.org/10.1007/s12633-024-02891-3.

Botelho, Chirlene N., et al. Evaluation of a photoelectrochemical platform based on strontium titanate, sulfur doped carbon nitride and palladium nanoparticles for detection of SARS-CoV-2 spike glycoprotein S1. Biosensors and Bioelectronics: X 11, 100167 (2022); https://doi.org/10.1016/j.biosx.2022.100167.

H.K. Jaafar, A. Hashim, & B.H. Rabee, Tailoring the Influence of Hybrid SiC/SrTiO3 Nanomaterials Doped PMMA/PEO for Promising Nanodielectric and Nanoelectronic Applications. Silicon, 16, 1905 (2024); https://doi.org/10.1007/s12633-023-02796-7.

Eman Abdul Rahman Assirey, Perovskite synthesis, properties and their related biochemical and industrial application. Saudi Pharmaceutical Journal, 27(6) 817‏ (2019); https://doi.org/10.1016/j.jsps.2019.05.003.

Hao Zheng et al. Cryptomelane-type manganese oxide (KMn8O16) nanorods cathode materials synthesized by a rheological phase for lithium ion batteries. IOP Conference Series: Earth and Environmental Science. 108. (2), 022012 (2018);‏ https://doi.org/10.1088/1755-1315/108/2/022012.

Zhengquan Li, et al. Rational growth of various α-MnO2 hierarchical structures and β-MnO2 nanorods via a homogeneous catalytic route. Crystal growth & design, 5(5), 1953 (2005); https://doi.org/10.1021/cg050221m.

Arava Lee la Mohana Reddy, et al. Coaxial MnO2/carbon nanotube array electrodes for high-performance lithium batteries. Nano letters, 9 (3), 1002 (2009); https://doi.org/10.1021/nl803081j.

H.A.J. Hussien, R.G. Kadhim, & A. Hashim, Investigating the low cost photodegradation performance against organic Pollutants using CeO2/MnO2/ polymer blend nanostructures. Opt Quant Electron, 54, 704 (2022); https://doi.org/10.1007/s11082-022-04094-9.

Jang Myoun Ko, and Man Kim Kwang, Electrochemical properties of MnO2/activated carbon nanotube composite as an electrode material for supercapacitor. Materials Chemistry and Physics,114((2-3), 837 (2009);‏ https://doi.org/10.1016/j.matchemphys.2008.10.047.

Zhangpeng Li et al. Synthesis of hydrothermally reduced graphene/MnO2 composites and their electrochemical properties as supercapacitors. Journal of Power Sources, 196(19), 8160 (2011); https://doi.org/10.1016/j.jpowsour.2011.05.036.

‏ Mingjun Pang et al. Rapid synthesis of graphene/amorphous α-MnO2 composite with enhanced electrochemical performance for electrochemical capacitor. Materials Science and Engineering: B 194, 41‏ (2015); https://doi.org/10.1016/j.mseb.2014.12.028.

H.A.J. Hussien, R.G. Kadhim, & A. Hashim, Tuning the optical characteristics of SiO2/MnO2 nanostructures doped organic blend for photodegradation of organic dyes. Opt Quant Electron, 53, 501 (2021); https://doi.org/10.1007/s11082-021-03157-7.

H.A.J. Hussien, R.G. Kadhim, & A. Hashim, Augmented structural and optical characteristics of SnO2/MnO2-doped PEO/PVP blend for photodegradation against organic pollutants. Polym. Bull. 79, 5219 (2022); https://doi.org/10.1007/s00289-021-03778-8.

‏ Hasan H. Mahdi, Black Carbon Incorporation Effect on Optical Properties of Poly-Methyl Methacrylate Films. European Journal of Advances in Engineering and Technology, 4 (10), 773‏ (2017).

Tagreed K.Hamad et al. Laser Induced Modification of the Optical Properties of Nano‐ZnO Doped PVC Films. International Journal of Polymer Science, 2014 (1), 96. (2014); https://doi.org/10.1155/2014/787595.

T. Abdel-Baset, M. Elzayat, and S. Mahrous. Characterization and optical and dielectric properties of polyvinyl chloride/silica nanocomposites films. International Journal of Polymer Science, 2016(1), 1707018 (2016); https://doi.org/10.1155/2016/1707018.

Sagadevan Suresh, Investigation of the optical and dielectric properties of the urea L-malic acid NLO single crystal. Am. Chem. Sci. J, 3(3), 325 (2013).

K.C. Lalithambika, K. Shanthakumari, and SriramSriram. Optical properties of CdO thin films deposited by chemical bath method. Int J Chemtech Res, 6(5), 3071‏ (2014).

Peshawa O.Amin, et al. Synthesis, spectroscopic, electrochemical and photophysical properties of high band gap polymers for potential applications in semi-transparent solar cells. BMC chemistry, 15, 1 (2021); https://doi.org/10.1186/s13065-021-00751-4.

Omed Gh Abdullah, K. Aziz Bakhtyar, and Mohammed Salh Dler. Structural and optical properties of PVA: Na2S2O3 polymer electrolytes films. Indian Journal of Applied Research, 3(11), 477 (2013); https://doi.org/10.15373/2249555X/NOV2013/153.

S. Choudhary, Dielectric dispersion and relaxations in (PVA-PEO)-ZnO polymer nanocomposites. Physica B: Condensed Matter, 522, 48 (2017); https://doi.org/10.1016/j.physb.2017.07.066.

Hayder Abduljalil, Ahmed Hashim, Alaa Jewad, The Effect of Addition Titanium Dioxide on Electrical Properties of Poly-Methyl Methacrylate, European Journal of Scientific Research, 63(2), 231 (2011).

Zein K. Heiba, Mohamed Bakr Mohamed, Sameh.I. Ahmed, Exploring the physical properties of PVA/PEG polymeric material upon doping with nano gadolinium oxide, Alexandria Engineering Journal, Volume 61, Issue 5, 2022, Pages 3375-3383, https://doi.org/10.1016/j.aej.2021.08.051.

Majeed Ali Habeeb, Ahmed Hashim, Aseel Hadi, Fabrication of New Nanocomposites: CMC-PAA-PbO2 Nanoparticles for Piezoelectric Sensors and Gamma Radiation Shielding Applications, Sensor Letters, 15 (9); 785(2017); https://doi.org/10.1166/sl.2017.3877.

Chetna Tyagi, and Devi Ambika. Alteration of structural, optical and electrical properties of CdSe incorporated polyvinyl pyrrolidone nanocomposite for memory devices. Journal of advanced dielectrics, 8(3), 1850020 (2018); https://doi.org/10.1142/S2010135X18500200.

H. Ahmed, A. Hashim, Tunable spectroscopic, electronic and thermal characteristics of PS/Nb5Si3/ZnS nanostructures for optics and potential nanodevices. Opt Quant Electron, 55, 9 (2023); https://doi.org/10.1007/s11082-022-04273-8.

Husam Miqdad, Effect of Carbon Black Nanoparticles on the Optical Properties of poly (ethylene oxide) Films. International Journal of Applied Engineering Research, 13(6), 4333‏ (2018).

S. Alharthi, Sami, et al. Exploring the functional properties of PVP/PVA blend incorporated with non-stoichiometric SnS for optoelectronic devices. Journal of Taibah University for Science, 16(1), 317 (2022); https://doi.org/10.1080/16583655.2022.2045766.

Shaymaa Hadi, Ahmed Hashim and Alaa Jewad, Optical properties of (PVA-LiF) composites, Australian Journal of Basic and Applied Sciences, l.5(9), 2192 (2011).

A. Hashim, A. Hadi, Novel lead oxide polymer nanocomposites for nuclear radiation shielding applications, Ukrainian Journal of Physics, 62(11), (2017); https://doi.org/10.15407/ujpe62.11.0978.

Ali F.Al-Shawabkeh, M. Elimat Ziad, and N. Abushgair Khaleel, Effect of non-annealed and annealed ZnO on the optical properties of PVC/ZnO nanocomposite films. Journal of Thermoplastic Composite Materials, 36(3), 899 (2023); https://doi.org/10.1177/08927057211038631.

Gulstan S.Ezat, Sarkawt A. Hussen, and Shujahadeen B. Aziz, Structure and optical properties of nanocomposites based on polystyrene (PS) and calcium titanate (CaTiO3) perovskite nanoparticles, Optik, 241 166963‏ (2021); https://doi.org/10.1016/j.ijleo.2021.166963.