Structural and electrical properties of sulfur-doped graphene oxide/graphite oxide composite

Array

Authors

  • R.G. Abaszade Azerbaijan State Oil and Industry University, Baku, Azerbaijan
  • A.G. Mamedov Azerbaijan State Oil and Industry University, Baku, Azerbaijan
  • I.Y. Bayramov Azerbaijan State Oil and Industry University, Baku, Azerbaijan
  • E.A. Khanmamadova Azerbaijan State Oil and Industry University, Baku, Azerbaijan
  • V.O. Kotsyubynsky Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine
  • O.A. Kapush V.E. Lashkarev Institute of Semiconductor Physics NAS of Ukraine, Kyiv, Ukraine
  • V.M. Boychuk Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine
  • E.Y. Gur Ataturk University, Erzurum, Turkey

DOI:

https://doi.org/10.15330/pcss.23.2.256-260

Keywords:

graphene oxide, graphite oxide, nanocomposite, negative differential resistance

Abstract

The sulfur-doped graphene oxide/graphite oxide composite material was synthesized in an original way, and a detailed study of its structural arrangement was carried out using XRD and Raman spectroscopy. Negative differential resistive properties of the obtained material were observed on the current-voltage curve at room temperature as a result of limited proton hopping through water molecules adsorbed on the hydrophilic surface of graphene oxide layers in the presence of a sulfur-enriched graphite oxide component with high electron conductivity, which promotes spatial charge separation and increases the efficiency of H+ transport. The obtained result offers a new way for the one-pot synthesis of new graphene-based composite materials with a wide range of possible applications.

References

F. Perrozzi, S. Prezioso, L. Ottaviano, Graphene oxide: From fundamentals to applications, J. Phys. Condens. Matter. 27, 013002 (2014); https://doi.org/10.1088/0953-8984/27/1/013002.

V.M. Boychuk, V.O. Kotsyubunsky, K.V. Bandura, B.I. Rachii, I.P. Yaremiy, S.V. Fedorchenko, Structural and electrical properties of nickel-iron spinel/reduced graphene oxide nanocomposites, Molecular Crystals and Liquid Crystals 1(1), 137 (2019); https://doi.org/10.1080/15421406.2019.1578503.

S. Vasileiadis, Z. Ziaka, Small scale reforming separation systems with nanomembrane reactors for direct fuel cell applications, J. Nano R 12, 105 (2010); https://doi.org/10.4028/www.scientific.net/JNanoR.12.105.

J. Abraham, K.S. Vasu, C.D. Williams, K. Gopinadhan, Y. Su, C.T. Cherian, J. Dix, E. Prestat, S.J. Haigh, I.V. Grigorieva, P. Carbone, A.K. Geim, R.R. Nair, Tunable sieving of ions using graphene oxide membranes, Nat. Nanotechnol. 12, 546 (2017); https://doi.org/10.1038/nnano.2017.21.

R.G. Abaszade, S.A. Mamedova, F.H. Agayev, S.I. Budzulyak, O.A. Kapush, M.A. Mamedova, A.M. Nabiyev, V.O. Kotsyubynsky, Synthesis and Characterization of Graphene Oxide Flakes for Transparent Thin Films, Physics and Chemistry of Solid State 22(3), 595 (2021); https://doi.org/10.15330/pcss.22.3.595-601.

E. Aliyev, V. Filiz, M. M. Khan, Y. J. Lee, C. Abetz, V. Abetz, Structural characterization of graphene oxide: Surface functional groups and fractionated oxidative debris, Nanomaterials 9(8), 1180, (2019); https://doi.org/10.3390/nano9081180.

S.R. Figarova, E.M. Aliyev, R.G. Abaszade, R.I. Alekberov, V.R. Figarov, Negative Differential Resistance of Graphene Oxide / Sulphur Compound, Journal of Nano Research 67, 25 (2021); https://doi.org/10.4028/www.scientific.net%2FJNanoR.67.25.

S.R. Figarova, G.N. Hasiyeva, V.R. Figarov, Negative differential conductivity in quantum well with complex potential profile for electron–phonon scattering, Physica E: Low-dimensional Systems and Nanostructures 78, 10 (2016); http://dx.doi.org/10.1016/j.physe.2015.11.036.

P. Sharma, L.S. Bernard, A. Bazigos, A. Magrez, A.M. Ionescu, Room-temperature negative differential resistance in graphene field effect transistors: experiments and theory, ACS nano 9(1), 620 (2015); https://doi.org/10.1021/nn5059437.

S. Rathi, I. Lee, M. Kang, D. Lim, Y. Lee, S. Yamacli, G.H. Kim, Observation of negative differential resistance in mesoscopic graphene oxide devices, Scientific reports 8(1), 1 (2018); https://doi.org/10.1038/s41598-018-22355-0.

I. Banerjee, P. Harris, A. Salimian, A.K. Ray, Graphene oxide thin films for resistive memory switches, IET Circuits, Devices & Systems 9(6), 428 (2015); https://doi.org/10.1049/iet-cds.2015.0170.

E.M. Aliyev, M.M. Khan, A.M. Nabiyev, R.M. Alosmanov, I.A. Bunyad-zadeh, S. Shishatskiy, V. Filiz, Covalently Modified Graphene Oxide and Polymer of Intrinsic Microporosity (PIM- in Mixed Matrix Thin-Film Composite Membranes, Nanoscale Research Letters 13, 359 (2018); https://dx.doi.org/10.1186%2Fs11671-018-2771-3.

L. Stobinski, B. Lesiak, A. Malolepszy, M. Mazurkiewicz, B. Mierzwa, J. Zemek, I. Bieloshapka, Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods, Journal of Electron Spectroscopy and Related Phenomena 195, 145 (2014); https://doi.org/10.1016/j.elspec.2014.07.003.

M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, L.G. Cancado, A. Jorio, R. Saito, Physical chemistry chemical physics, Studying disorder in graphite-based systems by Raman spectroscopy 9(11), 1276 (2007); https://doi.org/10.1039/B613962K.

S. Drewniak, R. Muzyka, A. Stolarczyk, T. Pustelny, M. Kotyczka-Morańska, M. Setkiewicz, Studies of reduced graphene oxide and graphite oxide in the aspect of their possible application in gas sensors, Sensors 16(1), 103 (2016); https://doi.org/10.3390/s16010103.

V.O. Kotsyubynsky, V.M. Boychuk, I.M. Budzulyak, B.I. Rachiy, M.A. Hodlevska, A.I. Kachmar, M.A. Hodlevsky, Graphene oxide synthesis using modified Tour method, Advances in Natural Sciences: Nanoscience and Nanotechnology 12(3), 035006 (2021); http://doi.org/10.1088/2043-6262/ac204f.

Z. Tian, J. Li, G. Zhu, J. Lu, Y. Wang, Z. Shi, C. Xu, Facile synthesis of highly conductive sulfur-doped reduced gra¬phene oxide sheets, Physical Chemistry Chemical Physics 18(2), 1125 (2016); https://doi.org/10.1039/C5CP05475C.

Z. Wang, P. Li, Y. Chen, J. He, W. Zhang, O.G. Schmidt, Y. Li, Pure thiophene–sulfur doped reduced graphene oxide: synthesis, structure, and electrical properties, Nanoscale 6(13), 7281 (2014); https://doi.org/10.1039/C3NR05061K.

Downloads

Published

2022-05-15

How to Cite

Abaszade, R., Mamedov, A., Bayramov, I., Khanmamadova, E., Kotsyubynsky, V., Kapush, O., … Gur, E. (2022). Structural and electrical properties of sulfur-doped graphene oxide/graphite oxide composite: Array. Physics and Chemistry of Solid State, 23(2), 256–260. https://doi.org/10.15330/pcss.23.2.256-260

Issue

Section

Scientific articles (Physics)

Most read articles by the same author(s)

1 2 3 > >>