The Mechanisms of Nickel-Iron Spinel Phase Nucleation in Aquous Solutions: Crystal Quasichemical Approach

Authors

  • V. Boychuk Vasyl Stefanyk Precarpathian National University
  • V. Kotsyubynsky Vasyl Stefanyk Precarpathian National University
  • K. Bandura Ivano-Frankivsk National Medical University
  • M. Hodlevska Vasyl Stefanyk Precarpathian National University
  • B. Dzundza Vasyl Stefanyk Precarpathian National University
  • O. Khatsevych Vasyl Stefanyk Precarpathian National University

DOI:

https://doi.org/10.15330/pcss.20.2.156-164

Keywords:

defect nickel-iron spinel, hydroxocomplex, lattice parameter, optical spectroscopy

Abstract

The phenomenological model of nikel-iron spinel nucleation with spinel structure based on the partial charge theory and analysis of hydrolysis and polycondensation processes at the interaction of Fe3+-, Fe2+- and Ni2+- hydroxocomplexes at different pH values of reaction medium was proposed. UV-vis optical spectroscopy was used for verification of the obtained results about the regularities of hydroxocomplexes formation. Crystal quasichemistry approach was applied for nucleation of nikel-iron spinel under the conditions of predomination of different defect types in NixFe3-xO4-δ (δ is oxygen non-stoichiometry) spinel lattice. The analysis of changes in electrical conductivity and lattice parameter of defect nickel-iron spinel as a function of Ni2+ atomic concentration was done for different values of d parameter.

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Published

2019-07-10

How to Cite

Boychuk, V., Kotsyubynsky, V., Bandura, K., Hodlevska, M., Dzundza, B., & Khatsevych, O. (2019). The Mechanisms of Nickel-Iron Spinel Phase Nucleation in Aquous Solutions: Crystal Quasichemical Approach . Physics and Chemistry of Solid State, 20(2), 156–164. https://doi.org/10.15330/pcss.20.2.156-164

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Scientific articles