Твердофазні рівноваги та термодинамічні властивості системи Sb-Te-S

Автор(и)

  • Ф.Р. Алієв Азербайджанський державний університет нафти та промисловості, Баку, Азербайджан
  • Е.Н. Оруйлу Азербайджанський державний університет нафти та промисловості (ASOIU), Азербайджан, Баку
  • Л.Ф. Машадієва Інститут каталізу та неорганічної хімії (ICIC), Азербайджан, Баку
  • Г.Б. Дашдієва Бакинський інженерний університет (BEU), Азербайджан, Баку
  • Д.М. Бабанли Франко - Азербайджанський університет (UFAZ), Азербайджан, Баку

DOI:

https://doi.org/10.15330/pcss.25.1.26-34

Ключові слова:

сульфід сурми, телурид сурми, Sb2Te2S, тетрадиміт, вимірювання ЕРС, термодинамічні властивості

Анотація

Для дослідження системи Sb–Te–S в області складу Sb2S3-Sb2Te3-Te-S в інтервалі температур 300–450 K використано порошковий рентгенівський аналіз (PXRD), а також вимірювання електрорушійної сили (ЕРС). Розраховано відносні парціальні молярні функції сурми в сплавах та відповідні дані використано для отримання самоузгоджених наборів стандартної вільної енергії Гіббса, стандартної ентальпії та стандартної ентропії сполук Sb2S3 і Sb2Te2S, а також твердих розчинів Sb2Te2,4S0,6 та Sb2Te2,7S0,3. Дані, отримані для Sb2S3, порівнювали із наявними в літературі. Вперше визначено термодинамічні функції сполуки Sb2Te2S, а також твердих розчинів Sb2Te2,4S0,6 та Sb2Te2,7S0,3.

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Опубліковано

2024-02-04

Як цитувати

Алієв, Ф., Оруйлу, Е., Машадієва, Л., Дашдієва, Г., & Бабанли, Д. (2024). Твердофазні рівноваги та термодинамічні властивості системи Sb-Te-S. Фізика і хімія твердого тіла, 25(1), 26–34. https://doi.org/10.15330/pcss.25.1.26-34

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