Influence of Element Concentration on Kinetic and Dynamic Properties of High-Entropy Solid Solutions

Editorial Board PCSS Journal; Н.І. Шумакова; С.І. Проценко; В.І. Шевченко; І.Ю. Проценко

doi:10.15330/pcss.26.4.964-970

Автор(и)

Н.І. Шумакова Сумський державний університет, м. Суми, Україна
С.І. Проценко Сумський державний університет, м. Суми, Україна
В.І. Шевченко Сумський державний університет, м. Суми, Україна
І.Ю. Проценко Сумський державний університет, м. Суми, Україна

DOI:

https://doi.org/10.15330/pcss.26.4.964-970

Ключові слова:

Високоентропійні сплави, Тверді розчини, Параметр решітки, Температура Дебая, Питомий опір, Середня довжина вільного пробігу, Плівка, Кореляція, Параметр різниці атомних радіусів

Анотація

Previously obtained calculation data on the dependence of dynamic characteristics (lattice parameter (a) and Debye temperature θ_D) and experimental data on kinetic characteristics (resistivity ρ and mean free path of electrons λ) on the concentration of elements in high-entropy alloys (HEAs) were generalized. In the first case, calculations were carried out for bulk solid solutions with an FCC lattice based on Cu, Co, Ni, Fe, Cr, Al, or Ti atoms; in the second case, on the basis of experimental data.

A correlation was established between θ_D and a, and between ρ and λ^-1 in four- and five-component solid solutions, in which Al and Ti atoms are absent. The reason for the unsatisfactory correlation in the presence of Al and Ti atoms is explained by the relatively large value of the parameter δ – the difference in atomic radii (5.2–7.1%) in solid solutions containing Al and Ti atoms. The individual parameter has an even larger value: 10.3% (Al) or 12.0–15.4% (Ti). Relatively large values of δ and can cause deformation of the solid-solution lattice, which manifests itself in the absence of correlation between θ_D and a, as well as between ρ and λ^-1.

Посилання

S.I. Vorobiov, D.M. Kondrakhova, S.A. Nepijko, N.I. Shumakova, I.Yu. Protsenko, Crystalline structure, electrophysical and magnetoresistive properties of high entropy film alloys, J. Nano- Electron. Phys., 8(3), 03026 (2016); https://doi.org/10.21272/jnep.8(3).03026.

L.V. Odnodvorets, Yu. Protsenko, Y.M. Shabelnyk, N.I. Shumakova, Correlation between the entropy degree and properties of multi-component (high-entropy) film materials, J. Nano- Electron. Phys. 12(2), 02014 (2020); https://doi.org/10.21272/jnep.12(2).02014.

I.Yu. Protsenko, L.V., Odnodvorets, M.V. Vasyukhno, A.K. Rylova, N.I. Shumakova, Concentration Effects in the Electronic Properties of High-entropy Film Alloys, J. Nano- Electron. Phys., 14(4), 04021 (2022); https://doi.org/10.21272/jnep.14(4).04021.

I.Yu. Protsenko, M.O. Shumakova, A.K. Rylova, N.I. Shumakova, The concentration dependences of lattice parameters and Debye temperature in multicomponent solid solutions Metallofizika i Noveishie Tekhnologii, 45(7), 857 (2023); https://doi.org/10.15407/mfint.45.07.0857.

S.I. Protsenko, L.V. Odnodvorets, N.I. Shumakova, O.O. Pasko, I.Yu. Protsenko, Concentration effects in multicomponent metallic solid solutions , Physics and Chemistry of Solid State, 2024, 25(2), 284 (2024); https://doi.org/10.15330/pcss.25.2.284-288.

I.Y. Protsenko, L.V. Odnodvorets, N.I. Shumakova, S.I. Protsenko, Y.M. Shabelnyk, A method of predicting the physical properties of multicomponent materials, European Physical Journal Plus, 139(3), 252 (2024); https://doi.org/10.1140/epjp/s13360-024-05030-4.

I.M. Pazukha, I.Yu. Protsenko, Theoretcal methods of investigation of thin film materials properties, Sumy, Sumy State University, 102 ( 2017).

Fizika tverdoho tela. Enciklopedicheskii slovar. Vol. 1 (Ed. by Bar'yakhtar V.G.) – Kyiv: Naukova dumka, 1996. – 656 p. [in Russian].

Fizika tverdoho tela. Enciklopedicheskii slovar. Vol. 2 (Ed. by Bar'yakhtarV.G.) – Kyiv: Naukova dumka, 1998. – 644 p. [in Russian].

Xiao Yang, Yong Zhang, Prediction of high-entropy stabilized solid-solution in multi-component alloys. Materials Chemistry and Physics, 132, 233 (2012); https://doi.org/10.1016/j.matchemphys.2011.11.021.

V. Cherniavsky, Generalized correlation of structure and mechanical properties formation in high entropy alloys of Al-Cu-Ni-Fe-Cr-Ti-V system during mechanical alloying and sintering, Avtoreferat dysertacii k.t.n., NTU “KPI”, Kyiv, 24 (2016).

Y. Zhang, X. Yang, P. K. Liaw, Alloy Design and Properties Optimization of High-Entropy Alloys, JOM, 64 (7), (2012); https://doi.org/10.1007/s11837-012-0366-5.

Sheng Guo, Qiang Hu, Chun Ng, C.T. Liu, More than entropy in high-entropy alloys: Forming solid solutions or amorphous phase, Intermetallics 41, 96 (2013); https://doi.org//10.1016/J.Intermet.2013.05.002.