Spectroscopic, Magnetic and Morphological studies of MgFe2O4 Nanopowder

Ф. Нааз; П. Лахірі; Ч. Кумарі; Х. Кумар Дубей

doi:10.15330/pcss.24.2.392-402

Автор(и)

Ф. Нааз Університет Банараса Хінду, Ванарас, Індія
П. Лахірі Університет Банараса Хінду, Ванарас, Індія
Ч. Кумарі Університет Банараса Хінду, Ванарас, Індія
Х. Кумар Дубей Коледж BRDPG, Деорія, Індія

DOI:

https://doi.org/10.15330/pcss.24.2.392-402

Ключові слова:

Spinel ferrite, Nanocrystalline, X-ray diffraction, Raman spectra, Magnetic properties

Анотація

Наноферитову сполуку типу шпінелі MgFe₂O₄ синтезовано золь-гель методом із використанням нітратів металів як прекурсорів. Фазовий склад, морфологію та елементний аналіз фериту магнію (MgFe₂O₄) здійснено методами дифракції Х-променів, перетворення Фур’є в інфрачервоному діапазоні, атомно-силової мікроскопії, енергодисперсійної Х-променевої та скануючої електронної мікроскопії.

Х-променева дифракційна картина зразка підтверджує існування однофазного матеріалу, для якого оцінка розмірів кристалітів склала 39,9 нм. Дослідження в інфрачервоному діапазоні із використанням перетворенням Фур’є підтвердило наявність коливань метал-кисень, що відповідають тетраедричним і октаедричним вузлам, відповідно. Із результатів скануючої електронної мікроскопії отримано розмір зерене, який склав приблизно 97,7 нм. Спектри комбінаційного розсіювання зразка демонструють п’ять активних мод раманівського розсіювання (A_1g + E_g + 3F_2g), що сумісно зі структурою шпінелі. Дослідження магнітних характеристик при кімнатній температурі показує поведінку петлі гістерезису з низьким значенням намагніченості насичення, 27,192 emu g^-1 і незначним значенням коерцитивної сили. Ширину забороненої зони визначено за допомогою спектрів пропускання в УФ-діапазону. Крім того, для підтвердження ступенів окислення та дослідження хімічного складу зразка використано методи рентгенівської фотоелектронної спектроскопії.

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