Features of Structural, Energy and Kinetic Characteristics of Hf1-xErxNiSn Solid Solution

Authors

  • L.P. Romaka Ivan Franko National University of Lviv
  • P.-F. Rogl Universitӓt Wien
  • A.M. Нoryn Ivan Franko National University of Lviv
  • V.V. Romaka National University “Lvivska Politechnika”
  • V.Ya. Krayovskyy National University “Lvivska Politechnika”
  • Yu.V. Stadnyk Ivan Franko National University of Lviv

DOI:

https://doi.org/10.15330/pcss.17.4.552-558

Keywords:

crystal and electronic structures, conductivity, thermopower coefficient

Abstract

1-xErxNiSn solid solution in the range: T = 80 – 400 K, x = 0 - 0.10. It was confirmed partly disorder crystal structure of HfNiSn compound as a result of occupation in the 4a crystallographic site of Hf (5d26s2) atoms by Ni (3d84s2) ones up to ~ 1 % that generates in the crystal structural defects of donor nature. It was shown that introduction of Er atoms ordered crystal structure (“healing” of structural defects). It was established mechanisms of simultaneous generation of structural defects as acceptors by substitution of Hf (5d26s2) by Er (4f125d06s2) atoms, and the donor nature defects as a result of the appearance of vacancies in the Sn (4b) atoms sites, which determines the mechanisms of conductivity for Hf1-xErxNiSn.

References

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Published

2016-12-15

How to Cite

Romaka, L., Rogl, P.-F., Нoryn A., Romaka, V., Krayovskyy, V., & Stadnyk, Y. (2016). Features of Structural, Energy and Kinetic Characteristics of Hf1-xErxNiSn Solid Solution. Physics and Chemistry of Solid State, 17(4), 552–558. https://doi.org/10.15330/pcss.17.4.552-558

Issue

Section

Scientific articles

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