Physical properties of nanocrystaline PbS synthesized by electrolytic method


  • O.А. Kapush Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine
  • N.V. Mazur Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine
  • A.V. Lysytsya Rivne State University of Humanities, Rivne, Ukraine
  • M.V. Moroz National University of Water Management and Environmental Management, Rivne, Ukraine
  • B.D. Nechyporuk Rivne State University of Humanities, Rivne, Ukraine
  • B.P. Rudyk National University of Water Management and Environmental Management, Rivne, Ukraine
  • V.M. Dzhagan Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Physics Department, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine
  • M.Ya. Valakh Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Physics Department, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine
  • V.O. Yukhymchuk Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine



lead sulfide, X-ray diffraction, nanocrystals, Debye-Scherrer formula, Williamson-Hall method, Raman scattering, phonons


The possibility of obtaining nanocrystaline lead sulfide by an electrolytic method using lead electrodes is demonstrated, and the influence of temperature on the synthesis process is investigated. Based on the results of X-ray diffraction studies, the chemical and phase composition of the obtained samples is determined, as well as the parameters of the unit cell of the crystals lattice. The size of the nanocrystallites and the magnitude of residual mechanical strain in them is determined using the methods of Debye-Scherrer and Williamson-Hall. The results of X-ray diffraction are in agreement with the results of the Raman scattering on phonons.


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How to Cite

Kapush, O., Mazur, N. ., Lysytsya, A., Moroz, M. ., Nechyporuk, B. ., Rudyk, B. ., … Yukhymchuk, V. (2023). Physical properties of nanocrystaline PbS synthesized by electrolytic method. Physics and Chemistry of Solid State, 24(2), 262–268.



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