The Effect of TiH2 Particle Size on its Properties

Authors

  • V.V. Moklyak G. V. Kurdyumov Institute for Metal Physics, National Academy of Sciences of Ukraine; Ivano-Frankivsk National Technical University of Oil and Gas, Ivano-Frankivsk, Ukraine
  • H.Yu. Mykhailova G.V. Kurdyumov Institute for Metal Physics, N.A.S. of Ukraine, Kyiv, Ukraine
  • M.M. Humeniak G.V. Kurdyumov Institute for Metal Physics, N.A.S. of Ukraine, Kyiv, Ukraine
  • V.A. Dekhtyarenko G.V. Kurdyumov Institute for Metal Physics, N.A.S. of Ukraine, Kyiv, Ukraine
  • O.O. Stasiuk G.V. Kurdyumov Institute for Metal Physics, N.A.S. of Ukraine, Kyiv, Ukraine

DOI:

https://doi.org/10.15330/pcss.27.1.95-100

Keywords:

TiH, powder, electric conductivity, composite

Abstract

Titanium-based composites have the potential to replace traditional materials in the automotive, aerospace and other industries. This is facilitated by their excellent mechanical, physical, thermal properties, and their strength-to-weight ratio.

In the presented work, the influence of the particle size of hydrogenated titanium on its conductive properties was investigated. Hydrogen saturation was carried out using the Stevenson apparatus, the hydrogen content was 3.8%. After that, the initial sample was subjected to high-energy grinding. 3 main particle sizes were identified for further research: 100 μm, 100-200 μm, over 200 μm.

Resistometric studies have shown that particles of 100-200 μm are characterized by an order of magnitude higher electrical conductivity than other particle sizes (8 (Ohm·cm)-1), which is due to the maximum contact between neighboring particles and their optimal geometry when packing the powder sample. Based on this powder size, a nanocomposite with carbon nanostructures was synthesized using mechanosynthesis, which is characterized by an order of magnitude higher electrical conductivity compared to the original components, which indicates the possibility of using such materials in the electrical engineering industry.

References

Bartłomiej Igliński, Urszula Kiełkowska, Krzysztof Mazurek, Sebastian Drużyński, Michał B. Pietrzak, Gopalakrishnan Kumar, Ashokkumar Veeramuthu, Mateusz Skrzatek, Marek Zinecker, Grzegorz Piechota, Renewable energy transition in Europe in the context of renewable energy transition processes in the world: A review, Heliyon, 10(24), e40997 (2024); https://doi.org/10.1016/j.heliyon.2024.e40997.

A. Neacsa, S.A. Rehman Khan, M. Panait, S.A. Apostu, The Transition to Renewable Energy—A Sustainability Issue?, In: Khan, S.A.R., Panait, M., Puime Guillen, F., Raimi, L. (eds) Energy Transition. Industrial Ecology, Springer, Singapore, (2022); https://doi.org/10.1007/978-981-19-3540-4_2.

Fred Huffman, Thermionic Energy Conversion, In: Meyers, R.A. (Ed.), Encyclopedia of Physical Science and Technology (3rd Edition), Academic Press, 627 (2003); https://doi.org/10.1016/B0-12-227410-5/00772-9.

D. Zabek, F. Morini, Solid state generators and energy harvesters for waste heat recovery and thermal energy harvesting, Thermal Science and Engineering Progress, 9, 235(2019); https://doi.org/10.1016/j.tsep.2018.11.011.

Ali Keçebaş, Muhammet Kayfeci, Hydrogen properties, In: Calise, F., Dentice D’Accadia, M., Santarelli, M., Lanzini, A., Ferrero, D. (eds) Solar Hydrogen Production, Academic Press, 3 (2019); https://doi.org/10.1016/B978-0-12-814853-2.00001-1.

Bellosta von Colbe J. J-R. Ares, J. Barale, M. Baricco, C. Buckley, G. Capurso, et al Application of hydrides in hydrogen storage and compression: Achievements, outlook and perspectives, Int J Hydrogen Energy, 44, 7780 (2019); https://doi.org/10.1016/j.ijhydene.2019.01.104.

J.G. Park, H.Y. Jang, S.C. Han, P.S. Lee, J.Y. Lee, Hydrogen storage properties of TiMn₂-based alloys for metal hydride heat pump, Mater. Sci. Eng. A-Struct., 329–331, 351– (2002); https://doi.org/10.1016/S0921-5093(01)01598-2.

M. Lototskyy, I. Tolj, Y. Klochko, M.W. Davids, D. Swanepoel, V. Linkov, Metal hydride hydrogen storage tank for fuel cell utility vehicles, Int. J. Hydrogen Energy, 45, 7958 (2020); https://doi.org/10.1016/j.ijhydene.2019.04.124.

V. A. Dekhtyarenko, D. G. Savvakin, V. I. Bondarchuk, V. M. Shyvaniuk, T. V. Pryadko, and O. O. Stasiuk, TiMn2-Based Intermetallic Alloys for Hydrogen Accumulation: Problems and Prospects, Progress in Physics of Metals, 22(3), 307 (2021): https://doi.org/10.15407/ufm.22.03.307.

A. Magliano, C. Perez Carrera, C.M. Pappalardo, D. Guida, V.P. Berardi, A Comprehensive Literature Review on Hydrogen Tanks: Storage, Safety, and Structural Integrity, Appl. Sci., 14, 9348 (2024); https://doi.org/10.3390/app14209348.

Q. Cheng, R. Zhang, Z. Shi, J. Lin, Review of common hydrogen storage tanks and current manufacturing methods for aluminium alloy tank liners, Int. J. Lightweight Mater. Manuf., 7(2), 269 (2024); https://doi.org/10.1016/j.ijlmm.2023.08.002.

О.М. Ivasishin, V.А. Dekhtyarenko, D.H. Savvakin, D.V. Oryshych, and V.I. Bondarchuk, Recent Trends in the Development of Ti–Zr-Based Alloys for Biomedical Applications and Hydrogenated Powder Technologies for Their Manufacturing, Progress in Physics of Metals, 26(3), 567 (2025); https://doi.org/10.15407/ufm.26.03.567.

H. Yu, A. Díaz, X. Lu, B. Sun, Y. Ding, M. Koyama, J. He, X. Zhou, A. Oudriss, X. Feaugas, Z. Zhang, Hydrogen Embrittlement as a Conspicuous Material Challenge─Comprehensive Review and Future Directions, Chem. Rev., 124(10), 6271 (2024);. https://doi.org/10.1021/acs.chemrev.3c00624.

X. Liu, H. Li, Y. Ma, X. Zhang, J. Hu, Y. Xu, G. Lei, S. Liu, Z. Cui, Y. Zhu, X. Li, H. Zheng, S. Geng, X. Chen, H. Liu, X. Wang, H. Liu, J. Cheng, C. Tang, Effect of hydrogen atoms adsorption on the work function of LaB6, Nucl. Mater. Energy, 44, 101959 (2025);. https://doi.org/10.1016/j.nme.2025.101959.

A. Rehman, R.W.E. van de Kruijs, W.T.E. van den Beld, J.M. Sturm, M. Ackermann, Work-Function-Dependent Reduction of Transition Metal Nitrides in Hydrogen Environments, J. Phys. Chem. Lett., 15(46), 11462 (2024); https://doi.org/10.1021/acs.jpclett.4c02259.

T. V. Pryadko, Features of Hydrogenation of the Ti—V System Alloys, Metallofiz. Noveishie Tekhnol., 37(2), 243 (2015); https://doi.org/10.15407/mfint.37.02.0243.

O.M. Ivasyshyn, D.H. Savvakin, Synthesis of Zirconium- and Titanium-Based Alloys with the Use of Their Hydrides. Mater Sci, 51, 465 (2016); https://doi.org/10.1007/s11003-016-9863-y.

Y.F. Zheng, X. Yao, Y.J. Su, D.L. Zhang, Fabrication of in situ TiC reinforced Ti matrix composites by thermomechanical consolidation of TiH₂/CNTs powder mixtures, Key Eng. Mater., 704, 55 (2016); https://doi.org/10.4028/www.scientific.net/KEM.704.55.

H.Yu. Mykhailova, E.G. Len, I.Ye. Galstyan, E.A. Tsapko, O.Yu. Gerasymov, V.I. Patoka, I.M. Sidorchenko, M.M. Yakymchuk, Electrical and Mechanical Properties of Composites Ti–Carbon Nanotubes, Metallofiz. Noveishie Tekhnol., 42(4), 575 (2020); https://doi.org/10.15407/mfint.42.04.0575.

X. Zhao, X. Ren, Z. Chen, C. Ge, Enhancement of mechanical and electrical properties of copper matrix composites by different types of carbon nanotubes, Mater. Charact., 218(2), 114575 (2024); https://doi.org/10.1016/j.matchar.2024.114575.

H.Y. Mykhailova, V.A. Dekhtyarenko, Y.V. Vasylyk, Hydrogen sorption properties of Ti15.4Zr30.2Mn(54.4−x−y)VxCryNiy alloy able of being activated at room temperature and pressure of 0.23 MPa, MRS Commun., 13, 1288 (2023); https://doi.org/10.1557/s43579-023-00451-1.

V.A. Dekhtyarenko, Composite material based on Laves phase with magnesium for hydrogen storage, MRS Commun., 14, 337 (2024); https://doi.org/10.1557/s43579-024-00534-7.

M. M. Nishchenko, G.Yu. Mikhaylova, E.I. Arkhipov, V.Yu. Koda, G.P. Prikhod'ko, Conductivity of multiwall carbon nanotubes array in process of compression strain. Metallofizika i Noveishie Tekhnologii, 31(4), 437 (2009).

M.M. Nyshchenko, H.Yu. Mykhailova, B.V. Kovalchuk, I.M. Sydorchenko, V.V. Anikeev, M.Ya. Shevchenko, V.M. Poroshyn, G.P. Prykhodko, Thermoelectric Properties of an Array of Carbon Nanotubes under Uniaxial Compression after Annealing, Metallofiz. Noveishie Tekhnol., 40(2), 169 (2018); https://doi.org/10.15407/mfint.40.02.0169.

A. Cooper, W.W. Erikson, M.S. Oliver, Electrical conductivity of porous binary powder mixtures, Mech. Mater., 162, 104026 (2021); https://doi.org/10.1016/j.mechmat.2021.104026.

H.Y. Mykhailova, M.Y. Shevchenko, Optimization of electronic properties of carbon nanostructures, Appl. Nanosci., 13, 7001 (2023); https://doi.org/10.1007/s13204-023-02842-1.

J.M. Montes, F. Gómez Cuevas, J. Cintas, F. Ternero, E. Sánchez Caballero, Electrical Resistivity of Powdered Porous Compacts, In: Electrical and Electronic Properties of Materials, IntechOpen, (2019); https://doi.org/10.5772/intechopen.76159.

A. Yildiz, S.B. Lisesivdin, M. Kasap, D. Mardare, Electrical properties of TiO₂ thin films, J. Non-Cryst. Solids, 354(45–46), 4944 (2008); https://doi.org/10.1016/j.jnoncrysol.2008.07.009.

I. Paulin, Č. Donik, D. Mandrino, M. Vončina, M. Jenko, Surface characterization of titanium hydride powder, Vacuum, 86(6), 608 (2012); https://doi.org/10.1016/j.vacuum.2011.07.054.

M.D. Hayat, H. Singh, Z. He, P. Cao, Titanium metal matrix composites: An overview, Compos. Part A: Appl. Sci. Manuf., (2019); https://doi.org/10.1016/j.compositesa.2019.04.005.

H.Yu. Mykhailova, E.G. Len, M.M. Yakymchuk, V.A. Dekhtyarenko, I.Ye. Galstian, M.Ya. Shevchenko, O.Yu. Gerasymov, E.A. Tsapko, V.I. Patoka, M.O. Rud, Electrophysical Properties of Composites Based on Hydrogenated Titanium with Different Contents of Thermally Expanded Graphite, Metallofiz. Noveishie Tekhnol., 44(11), 1523 (2022); https://doi.org/10.15407/mfint.44.11.1523.

I.Ye. Galstian, E.G. Len, E.A. Tsapko, H.Yu. Mykhailova, V.Yu. Koda, M.O. Rud, M.Ya. Shevchenko, V.I. Patoka, M.M. Yakymchuk, G.O. Frolov, Low-Temperature Thermionic Converters Based on Metal–Nanostructured Carbon Composites, Metallofiz. Noveishie Tekhnol., 42(4), 451 (2020); https://doi.org/10.15407/mfint.42.04.0451.

I. Galstian, H.Yu. Mykhailova, E.G. Len, et al., The Effect of Hydrogen Content on Electrophysical Properties of Hydrogenated Titanium–Thermally Expanded Graphite Composites, Preprint, Research Square, (2023); https://doi.org/10.21203/rs.3.rs-3138375/v1.

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Published

2026-03-08

How to Cite

Moklyak, V., Mykhailova, H., Humeniak, M., Dekhtyarenko, V., & Stasiuk, O. (2026). The Effect of TiH2 Particle Size on its Properties. Physics and Chemistry of Solid State, 27(1), 95–100. https://doi.org/10.15330/pcss.27.1.95-100

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Scientific articles (Physics)

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